Table 1.
Exploring the effect of C2‐substituent and nucleophile on C‐glycosylationa
Reactions were performed with the specified lactone (LX) (0.1 mmol, 1.0 equiv.) and the specified nucleophile (0.11 mmol, 1.1 equiv.) in 0.58 mL of THF.
Selectivity determined by 19F NMR analysis of the crude reaction mixture.
1:1 mixture of diastereomers with respect to the sec‐butyl moiety.