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a) Average K cis/trans values in model systems 10–14. [a] From each replica, ΔG=−RT ln(K cis/trans) at 25 °C. Averages and standard deviation values are given for n=6 or n=4 (b). b) Average K cis/trans values vs. the number of fluorine atoms present (n f). c) Correlation between ΔG cis/trans and Cα‐substituent field/inductive constants (σ I). d) Schematic representation of the proposed peptoid cis‐amide isomer stabilization by inductive factors. e) Inductive constants of Cα groups.15
