Table 2.
Volatile compounds profile extracted by using HS-SPME and GC/MS from CBD oils samples.
| Oil Samples | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | ||||||||||
| Matrix | FU Oil | Hemp Seed Oil | Olive Oil | MCT Oil | Olive Oil | Hemp Seed Oil | Olive Oil | Hemp Seed Oil | ||||||||||
| RI a | R.T b | Compound |
Average
c
μg/g |
SD
(±) |
Average c
μg/g |
SD
(±) |
Average c
μg/g |
SD
(±) |
Average c
μg/g |
SD
(±) |
Average c
μg/g |
SD
(±) |
Average c
μg/g |
SD
(±) |
Average c
μg/g |
SD
(±) |
Average c
μg/g |
SD
(±) |
| Alcohols | ||||||||||||||||||
| 831 | 20.63 | 1-Hexanol | 2.08 | 0.14 | 5.15 | 0.71 | n.d. | - | n.d. | - | 2.55 | 0.16 | 8.10 | 0.12 | 2.58 | 0.03 | 11.52 | 0.37 |
| 868 | 21.43 | 3-Hexen-1-ol | 0.66 | 0.07 | 0.67 | 0.11 | n.d. | - | 0.55 | 0.02 | 1.47 | 0.08 | 1.46 | 0.04 | 1.76 | 0.05 | n.d. | - |
| 849 | 22.02 | 2-Hexen-1-ol | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 0.77 | 0.11 | n.d. | - | 1.10 | - | n.d. | - |
| 969 | 23.07 | 1-Octen-3-ol | n.d. | - | 3.90 | 0.47 | n.d. | - | n.d. | - | 0.73 | 0.15 | 1.73 | 0.03 | 1.09 | 0.51 | n.d. | - |
| 960 | 23.17 | 1-Heptanol | n.d. | - | 0.83 | 0.13 | n.d. | - | n.d. | - | 0.50 | 0.01 | 2.49 | 0.10 | n.d. | - | n.d. | - |
| 1059 | 25.48 | 1-Octanol | n.d. | - | n.d. | - | 1.29 | 0.11 | n.d. | - | 0.59 | 0.03 | 5.23 | 0.63 | n.d. | - | n.d. | - |
| 1068 | 27.98 | 3,3,6-Trimethyl-1,5-heptadien-4-ol | 2.39 | 0.46 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 1036 | 31.59 | α-Toluenol | 0.42 | 0.03 | 2.74 | 0.59 | n.d. | - | n.d. | - | 2.36 | 0.16 | 3.96 | 0.47 | 3.22 | 0.23 | n.d. | - |
| 1136 | 32.06 | Benzeneethanol | 0.51 | 0.04 | 1.39 | 0.32 | n.d. | - | n.d. | - | 2.73 | 0.16 | 5.05 | 0.58 | 3.43 | 0.22 | 0.76 | 0.01 |
| Total | 6.06 | 14.68 | 1.29 | 0.55 | 11.70 | 28.01 | 13.18 | 12.28 | ||||||||||
| Aldehydes | ||||||||||||||||||
| 508 | 2.31 | Propanal | n.d. | - | n.d. | - | 0.77 | 0.03 | n.d. | - | 0.96 | 0.04 | 1.10 | 0.08 | 0.97 | 0.05 | n.d. | - |
| 574 | 3.23 | 2-Methyl-2-propenal | n.d. | - | n.d. | - | 0.61 | 0.03 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 643 | 3.74 | 2-Methyl-butanal | 1.73 | 0.02 | 0.56 | 0.02 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 643 | 3.83 | 3-Methyl-butanal | 0.90 | 0.16 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 785 | 10.12 | Hexanal | 0.70 | 0.02 | 5.57 | 0.14 | 10.15 | 0.29 | n.d. | - | 2.97 | 0.17 | 6.89 | 0.01 | 2.60 | 0.15 | 3.42 | 0.03 |
| 905 | 15.05 | Heptanal | 0.76 | 0.03 | n.d. | - | 1.03 | 0.03 | n.d. | - | n.d. | - | n.d. | - | 0.67 | 0.10 | 0.62 | 0.03 |
| 814 | 16.24 | 2-Hexenal | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 1.19 | 0.12 | n.d. | - | 1.41 | 0.03 | n.d. | - |
| 1005 | 18.74 | Octanal | n.d. | - | n.d. | - | 2.47 | 0.02 | n.d. | - | 2.03 | 0.23 | 17.40 | 0.16 | 1.87 | 0.03 | n.d. | - |
| 913 | 19.72 | 2-Heptenal | n.d. | - | 3.10 | 0.05 | 2.61 | 0.22 | n.d. | - | 1.86 | 0.09 | 6.44 | 0.41 | 1.59 | 0.03 | 1.22 | 0.05 |
| 1104 | 21.67 | Nonanal | 0.73 | 0.16 | n.d. | - | 2.63 | 0.30 | n.d. | - | n.d. | - | 4.92 | 0.03 | 1.07 | - | n.d. | - |
| 1013 | 22.53 | 2-Octenal | n.d. | - | n.d. | - | 0.68 | 0.05 | n.d. | - | n.d. | - | 2.07 | 0.08 | n.d. | - | 0.61 | 0.02 |
| 921 | 24.01 | 2,4-Heptadienal | n.d. | - | 1.27 | 0.05 | 0.74 | 0.14 | n.d. | - | n.d. | - | 7.97 | 0.34 | n.d. | - | n.d. | - |
| 982 | 24.77 | Benzaldehyde | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 1.86 | 0.01 | 25.84 | 0.45 | n.d. | - | n.d. | - |
| 1174 | 28.04 | 3,7-Dimethyl-2,6-octadienal | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 44.49 | 4.40 | n.d. | - | n.d. | - |
| Total | 4.82 | 10.50 | 21.68 | n.d. | 10.87 | 117.14 | 10.19 | 5.88 | ||||||||||
| Esters | ||||||||||||||||||
| 487 | 2.63 | Acetic acid-methyl ester | 0.78 | 0.02 | 0.72 | 0.04 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 586 | 3.33 | Acetic acid-ethyl ester | n.d. | - | 8.70 | 0.12 | 302.74 | 12.32 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 686 | 5.35 | Acetic acid-propyl ester | n.d. | - | n.d. | - | 1.45 | 0.07 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 721 | 6.77 | Acetic acid-2-methyl-propyl ester | n.d. | - | n.d. | - | 5.39 | 0.06 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 785 | 9.76 | Acetic acid-buthyl ester | n.d. | - | n.d. | - | 1.17 | 0.11 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 820 | 12.27 | 1-Butanol-3-methyl acetate | n.d. | - | n.d. | - | 7.46 | 0.17 | n.d. | - | n.d. | - | 16.98 | 0.21 | n.d. | - | n.d. | - |
| 992 | 19.62 | 3-Hexen-1-ol-acetate | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 0.64 | 0.02 | n.d. | - |
| 1183 | 22.24 | Butanoic acid-hexyl ester | n.d. | - | n.d. | - | n.d. | - | 0.60 | 0.02 | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| Total | 0.78 | 9.42 | 318.21 | 0.60 | n.d. | 16.98 | 0.64 | n.d. | ||||||||||
| Ketones | ||||||||||||||||||
| 455 | 2.50 | 2-Propanone | 1.76 | 0.13 | 3.50 | 0.47 | 8.56 | 0.57 | n.d. | - | 2.46 | 0.51 | 5.03 | 0.65 | 1.78 | 0.14 | 0.96 | 0.01 |
| 1161 | 13.19 | 1-(1,3-dimethyl-3-cyclohexen-1-yl)-Ethanone | n.d. | - | 1.89 | 0.18 | n.d. | - | n.d. | - | n.d. | - | 2.07 | 0.15 | n.d. | - | 0.90 | 0.06 |
| 853 | 14.89 | 2-Heptanone | n.d. | - | 3.32 | 0.09 | 0.71 | 0.02 | n.d. | - | 2.69 | 0.16 | n.d. | - | 2.74 | 0.06 | 1.00 | 0.06 |
| 952 | 18.57 | 2-Octanone | n.d. | - | 4.63 | 0.64 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 960 | 19.99 | 6-Octen-2-one | n.d. | - | 0.86 | 0.11 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 987 | 20.17 | 6-Methyl-5 hepten-2 one | 1.25 | 0.04 | 8.97 | 1.20 | 10.55 | 0.42 | n.d. | - | 2.28 | 0.11 | 17.04 | 0.14 | 1.63 | 0.00 | 2.26 | 0.13 |
| 960 | 21.96 | 3-Octen-2-one | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 962 | 22.51 | Ketone | 0.69 | 0.02 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 968 | 24.67 | 3,5-Octadien-2-one | n.d. | - | n.d. | - | 4.94 | 0.41 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| Total | 3.70 | 23.17 | 24.77 | n.d. | 7.44 | 24.14 | 6.15 | 5.12 | ||||||||||
| Terpenes | ||||||||||||||||||
| 939 | 6.67 | α-Pinene | 14.25 | 0.55 | 21.47 | 0.38 | n.d. | - | 73.23 | 9.63 | 112.95 | 1.47 | 5883.13 | 22.05 | 119.09 | 0.23 | 52.84 | 1.11 |
| 932 | 7.03 | α-Thujene | 0.98 | 0.17 | 1.18 | 0.08 | n.d. | - | 0.79 | 0.08 | 2.86 | 0.19 | 44.54 | 1.08 | 3.24 | 0.10 | n.d. | - |
| 961 | 8.67 | Camphene | n.d. | - | n.d. | - | n.d. | - | 0.94 | 0.27 | 1.57 | 0.09 | 65.97 | 3.91 | 1.60 | 0.01 | 0.95 | 0.03 |
| 989 | 10.75 | β-Pinene | 4.15 | 0.05 | 4.45 | 0.08 | n.d. | - | 23.36 | 4.71 | 35.65 | 2.06 | 625.28 | 4.35 | 37.08 | 0.48 | 17.91 | 0.28 |
| 985 | 11.66 | Sabinene | n.d. | - | 1.26 | 0.07 | n.d. | - | n.d. | - | 1.66 | 0.01 | 98.17 | 0.06 | 1.53 | 0.08 | n.d. | - |
| 879 | 11.74 | 2,4(10)-Thujadien | n.d. | - | 0.85 | 0.00 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 1017 | 12.99 | δ-3-Carene | 1.73 | 0.03 | 0.61 | 0.09 | n.d. | - | 7.42 | 1.33 | 50.22 | 1.18 | 4.69 | 0.31 | 51.31 | 2.68 | 6.17 | 0.50 |
| 1015 | 13.81 | α-Phellandrene | 3.70 | 0.14 | 3.90 | 0.09 | n.d. | - | 2.91 | 0.65 | 6.78 | 0.01 | 4.97 | 0.04 | 8.06 | 0.18 | 1.85 | 0.09 |
| 991 | 14.24 | β-Myrcene | 108.13 | 0.09 | 34.63 | 1.00 | 9.14 | 0.48 | 419.53 | 33.32 | 389.37 | 20.60 | 2908.00 | 60.01 | 419.01 | 6.04 | 189.05 | 1.74 |
| 1026 | 14.44 | α-Terpinene | 3.60 | 0.38 | 10.01 | 0.56 | n.d. | - | 2.44 | 0.07 | 5.51 | 0.17 | 34.87 | 3.09 | 6.82 | 0.12 | 1.74 | 0.01 |
| 1038 | 15.31 | Limonene | 6.05 | 0.01 | 8.03 | 0.44 | 1.60 | 0.07 | 65.17 | 7.36 | 23.67 | 1.33 | 8841.42 | 171.34 | 20.17 | 0.26 | 23.97 | 0.34 |
| 1045 | 15.49 | Eucalyptol | 3.67 | 0.01 | 5.60 | 0.35 | 7.15 | 0.26 | 2.65 | 0.13 | 4.18 | 0.27 | 13.66 | 1.60 | 3.09 | 0.07 | 8.62 | 0.12 |
| 946 | 15.61 | β-Phellandrene | 7.16 | 0.14 | 4.80 | 0.52 | n.d. | - | 8.40 | 0.80 | 19.02 | 1.05 | 61.90 | 4.71 | 20.05 | 0.16 | 7.38 | 0.22 |
| 976 | 17.05 | Cis-ocimene | 0.48 | 0.02 | 2.17 | 0.17 | 0.48 | 0.00 | 16.55 | 1.07 | 21.17 | 0.88 | 7.13 | 0.24 | 19.24 | 0.23 | 5.50 | 0.11 |
| 1066 | 17.15 | γ-Terpinene | 5.38 | 0.01 | 5.84 | 0.58 | 0.59 | 0.06 | 2.11 | 0.09 | 4.80 | 0.23 | 499.58 | 9.26 | 4.61 | 0.08 | 2.48 | 0.04 |
| 1000 | 17.24 | Terpene | n.d. | - | n.d. | - | 2.48 | 0.24 | n.d. | - | 2.59 | 0.02 | 17.49 | 0.05 | 1.82 | 0.04 | n.d. | - |
| 1029 | 17.60 | β-Ocimene | 21.75 | 1.08 | 7.55 | 0.53 | 9.96 | 0.48 | 194.00 | 21.13 | 192.39 | 5.19 | 22.82 | 0.17 | 213.15 | 1.26 | 42.00 | 1.72 |
| 1034 | 18.01 | p-Cymene | 3.13 | 0.11 | 8.53 | 0.97 | 0.81 | 0.01 | 2.98 | 0.33 | 12.37 | 0.05 | 144.55 | 1.92 | 10.02 | 0.15 | 5.62 | 0.09 |
| 1094 | 18.43 | α-Terpinolene | 62.12 | 0.67 | 7.48 | 0.80 | n.d. | - | 111.31 | 14.58 | 265.95 | 16.97 | 33.73 | 0.11 | 297.20 | 3.11 | 73.16 | 3.13 |
| 1177 | 22.74 | Para-cymenyl | 13.97 | 0.88 | 11.28 | 0.16 | n.d. | - | 3.30 | 0.82 | 64.48 | 5.97 | 134.94 | 1.32 | 49.21 | 0.39 | 4.70 | 0.24 |
| 1136 | 23.01 | Terpene | n.d. | - | n.d. | - | n.d. | - | 1.55 | 0.36 | 1.39 | 0.11 | n.d. | - | 1.43 | 0.05 | n.d. | - |
| 1083 | 23.35 | 4,8-Epoxy-p-menth-1-ene | 1.30 | 0.08 | 2.08 | 0.23 | n.d. | - | 2.22 | 0.03 | 6.44 | 0.16 | 3.08 | 0.03 | 5.20 | 0.60 | 1.32 | 0.01 |
| 1164 | 23.48 | Linalool oxide | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 1.11 | 0.03 | 17.95 | 0.94 | 1.51 | 0.01 | n.d. | - |
| 1221 | 23.68 | α-Ylangene | n.d. | - | 1.09 | 0.23 | n.d. | - | n.d. | - | 0.52 | 0.00 | 2.19 | 0.09 | n.d. | - | 1.18 | 0.07 |
| 1082 | 25.29 | β-Linalool | 5.52 | 0.81 | 2.22 | 0.32 | 10.55 | 1.27 | 0.82 | 0.01 | 5.19 | 0.01 | 1471.75 | 15.90 | 5.36 | 0.37 | n.d. | - |
| 1494 | 25.75 | γ-Caryophyllene | n.d. | - | 5.87 | 1.68 | 2.02 | 0.24 | 1.03 | 0.06 | 1.81 | 0.05 | 30.72 | 1.10 | 1.32 | 0.04 | 4.40 | 0.17 |
| 1430 | 26.03 | α-Bergamotene | 2.42 | 0.21 | 11.89 | 3.95 | 1.75 | 0.08 | 2.21 | 0.19 | 2.31 | 0.02 | 40.96 | 0.21 | 1.01 | 0.08 | 9.44 | 0.07 |
| 1456 | 26.12 | α-Guaiene | 2.46 | 0.05 | n.d. | - | 7.19 | 0.57 | n.d. | - | n.d. | - | 5.20 | 0.18 | n.d. | - | n.d. | - |
| 1494 | 26.23 | Trans-caryophyllene | 17.34 | 1.81 | 159.92 | 49.08 | 90.68 | 7.15 | 40.67 | 3.44 | 48.77 | 1.93 | 425.63 | 7.84 | 32.06 | 4.48 | 110.41 | 1.33 |
| Terpenes | ||||||||||||||||||
| 1209 | 26.40 | 4-Terpineol | 2.32 | 0.23 | 3.34 | 0.62 | 0.55 | 0.06 | n.d. | - | 2.80 | 0.24 | 15.34 | 1.66 | 1.71 | 0.18 | n.d. | - |
| 1440 | 26.59 | Sesquiterpene | n.d. | - | 3.03 | 0.70 | 1.37 | 0.18 | n.d. | - | 1.64 | 0.07 | 17.73 | 0.11 | n.d. | - | 1.13 | 0.10 |
| 1386 | 27.21 | Sesquiterpene | n.d. | - | 6.09 | 2.17 | n.d. | - | n.d. | - | 0.58 | 0.05 | 12.62 | 0.59 | n.d. | - | 7.01 | 0.26 |
| 1131 | 27.47 | Trans-pinocarveol | n.d. | - | 9.69 | 1.69 | n.d. | - | n.d. | - | 3.04 | 0.07 | 10.99 | 0.49 | 2.30 | 0.08 | 5.12 | 0.08 |
| 1482 | 27.73 | α-Humulene | 6.28 | 0.44 | 45.95 | 15.88 | 21.61 | 1.49 | 10.13 | 1.54 | 9.62 | 0.69 | 117.14 | 3.27 | 5.94 | 0.88 | 32.25 | 1.15 |
| 1189 | 28.13 | 1,8-Menthadien-4-ol | 6.23 | 1.02 | 21.18 | 4.16 | n.d. | - | 2.19 | 0.43 | 19.68 | 0.44 | 44.91 | 2.39 | 12.61 | 0.58 | 6.86 | 0.41 |
| 1209 | 28.32 | α-Terpineol | 2.79 | 0.43 | 3.31 | 0.85 | 1.13 | 0.02 | n.d. | - | 2.90 | 0.24 | 14.35 | 1.10 | 1.83 | 0.04 | 0.63 | 0.07 |
| 1189 | 28.40 | Borneol | 0.52 | 0.04 | 2.78 | 0.74 | n.d. | - | n.d. | - | 0.64 | 0.04 | 1.59 | 2.25 | n.d. | - | n.d. | - |
| 1490 | 28.65 | δ-Guaiene | 1.56 | 0.01 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 1519 | 28.72 | β-Selinene | 0.85 | 0.01 | 11.64 | 4.28 | 1.65 | 0.02 | 0.96 | 0.19 | 1.46 | 0.13 | 41.02 | 1.77 | 0.85 | 0.17 | 8.15 | 0.36 |
| 1522 | 28.82 | α-Selinene | 1.04 | 0.01 | 7.51 | 2.69 | 1.06 | 0.14 | n.d. | - | 1.04 | 0.06 | 26.41 | 1.64 | n.d. | - | 4.51 | 0.20 |
| 1474 | 28.98 | Sesquiterpene | n.d. | - | 1.88 | 0.58 | n.d. | - | n.d. | - | n.d. | - | 53.97 | 6.99 | n.d. | - | 0.92 | 0.02 |
| 1190 | 29.03 | Carvone | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 1507 | 29.86 | Selina-3,7(11)-diene | n.d. | - | 6.79 | 2.41 | n.d. | - | 0.96 | 0.31 | 1.85 | 0.06 | 25.33 | 2.61 | n.d. | - | 3.78 | 0.21 |
| 1191 | 30.13 | Myrtenol | n.d. | - | 1.49 | 0.26 | n.d. | - | n.d. | - | 0.94 | 0.04 | 3.18 | 0.40 | n.d. | - | 0.80 | 0.03 |
| 1284 | 31.17 | Cuminol | 4.00 | 0.64 | 7.44 | 1.98 | n.d. | - | 0.54 | 0.07 | 7.87 | 0.61 | 30.26 | 3.84 | 7.02 | 0.08 | 1.46 | 0.10 |
| 1322 | 33.41 | Humulene oxide | n.d. | - | 2.22 | 0.92 | 0.72 | 0.13 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 1.36 | 0.14 |
| 1419 | 34.11 | Sesquiterpene | n.d. | - | n.d. | - | 1.54 | 0.03 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 1392 | 34.86 | Eugenol | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 0.82 | 0.00 | 1.12 | 0.05 | 1.17 | 0.02 | n.d. | - |
| Total | 314.90 | 457.03 | 174.05 | 1000.37 | 1339.56 | 21860.3 | 1367.63 | 644.70 | ||||||||||
| Miscellaneous | ||||||||||||||||||
| 906 | 11.03 | 3,3,6-Trimethyl-1,5-heptadiene | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 11.87 | 0.33 | n.d. | - | n.d. | - |
| 907 | 12.72 | 1,3-Dimethyl-benzene | n.d. | - | 0.96 | 0.08 | n.d. | - | 2.17 | 0.38 | n.d. | - | 1.41 | 0.02 | n.d. | - | n.d. | - |
| 1040 | 16.87 | 2-Pentyl-furan | n.d. | - | 1.82 | 0.20 | n.d. | - | n.d. | - | 0.24 | 0.01 | 3.94 | 0.10 | n.d. | - | 1.99 | 0.07 |
| 1020 | 18.31 | 1,2,4,-Trimethyl-benzene | n.d. | - | n.d. | - | 1.35 | 0.38 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 894 | 19.54 | 2,5-Dimethyl-pyrazine | 1.03 | 0.05 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 1.23 | 0.04 | n.d. | - | n.d. | - |
| 891 | 19.74 | 2,6-Dimethyl-pyrazine | 0.82 | 0.03 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 1176 | 20.72 | 1,4-Bis (1-methylethyl)-benzene | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 1.81 | 0.01 | n.d. | - | n.d. | - |
| 985 | 21.89 | 2,6-Dimethyl-2,6-octadiene | n.d. | - | n.d. | - | 3.25 | 0.14 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 1081 | 22.10 | Diethyl carbitol | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| 1039 | 22.36 | 1,3,5-Trimethylenecycloheptane | n.d. | - | 1.07 | 0.26 | n.d. | - | 0.80 | 0.12 | 1.52 | 0.00 | 2.62 | 0.06 | 1.70 | 0.02 | n.d. | - |
| 986 | 28.45 | 5-Ethyldihydro-2(3H)-furanone | n.d. | - | 1.92 | 0.14 | n.d. | - | n.d. | - | 3.89 | 0.41 | 27.39 | 2.75 | 6.63 | 0.41 | 0.96 | 0.15 |
| 1190 | 30.85 | 1-Methoxy-4(1-propenyl)-benzene | n.d. | - | n.d. | - | n.d. | - | 3.22 | 0.07 | n.d. | - | n.d. | - | n.d. | - | n.d. | - |
| Total | 1.85 | 7.19 | 4.60 | 6.19 | 8.38 | 54.23 | 10.93 | 2.95 | ||||||||||
| Oil Samples | 9 | 10 | 11 | 12 | 13 | 14 | 15 | |||||||||||
| Matrix | Hemp Seed Oil | Olive Oil | Hemp Seed Oil | Hemp Seed Oil | Olive Oil | Hemp Seed Oil | Hemp Seed Oil | |||||||||||
| RI a | R.T b | Compound |
Average c
μg/g |
SD
(±) |
Average c
μg/g |
SD
(±) |
Average c
μg/g |
SD
(±) |
Average c
μg/g |
SD
(±) |
Average c
μg/g |
SD
(±) |
Average c
μg/g |
SD
(±) |
Averagec
μg/g |
SD
(±) |
||
| Alcohols | ||||||||||||||||||
| 831 | 20.63 | 1-Hexanol | 6.19 | 0.32 | 2.66 | 0.08 | 2.00 | 0.14 | 4.37 | 0.20 | 0.67 | 0.02 | 3.52 | 0.23 | 9.67 | 0.16 | ||
| 868 | 21.43 | 3-Hexen-1-ol | n.d. | - | 1.81 | 0.03 | n.d. | - | n.d. | - | 0.65 | 0.01 | 0.86 | 0.06 | n.d. | - | ||
| 849 | 22.02 | 2-Hexen-1-ol | n.d. | - | 1.15 | 0.05 | n.d. | - | 0.62 | 0.07 | 0.63 | 0.00 | n.d. | - | n.d. | - | ||
| 969 | 23.07 | 1-Octen-3-ol | 1.08 | 0.03 | 0.79 | 0.01 | 1.26 | 0.13 | 1.23 | 0.07 | n.d. | - | 1.35 | 0.00 | n.d. | - | ||
| 960 | 23.17 | 1-Heptanol | n.d. | - | n.d. | - | n.d. | - | 0.72 | 0.04 | n.d. | - | n.d. | - | n.d. | - | ||
| 1059 | 25.48 | 1-Octanol | n.d. | - | 0.58 | 0.11 | n.d. | - | n.d. | - | n.d. | - | 2.30 | 0.25 | n.d. | - | ||
| 1068 | 27.98 | 3,3,6-Trimethyl-1,5-heptadien-4-ol | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 1.56 | 0.10 | n.d. | - | ||
| 1036 | 31.59 | α-Toluenol | n.d. | - | 3.03 | 0.35 | n.d. | - | 1.39 | 0.15 | n.d. | - | 2.08 | 0.61 | n.d. | - | ||
| 1136 | 32.06 | Benzeneethanol | 0.62 | 0.03 | 3.07 | 0.62 | n.d. | - | 1.25 | 0.01 | 0.87 | 0.13 | 2.72 | 0.98 | n.d. | - | ||
| Total | 7.89 | 13.09 | 3.26 | 9.57 | 2.82 | 14.38 | 9.67 | |||||||||||
| Aldehydes | ||||||||||||||||||
| 508 | 2.31 | Propanal | n.d. | - | 1.04 | 0.00 | n.d. | - | n.d. | - | 0.97 | 0.02 | 0.62 | 0.10 | n.d. | - | ||
| 574 | 3.23 | 2-Methyl-2-propenal | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 643 | 3.74 | 2-Methyl-butanal | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 643 | 3.83 | 3-Methyl-butanal | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 785 | 10.12 | Hexanal | 6.35 | 0.40 | 2.53 | 0.01 | 10.51 | 0.36 | 7.04 | 0.29 | 3.18 | 0.36 | 2.60 | 0.18 | 1.80 | 0.12 | ||
| 905 | 15.05 | Heptanal | n.d. | - | 0.63 | 0.03 | 0.46 | 0.02 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 814 | 16.24 | 2-Hexenal | 1.23 | 0.06 | 1.41 | 0.03 | 1.02 | 0.02 | 0.53 | 0.75 | 11.50 | 0.40 | 0.82 | 0.04 | n.d. | - | ||
| 1005 | 18.74 | Octanal | n.d. | - | 1.92 | 0.07 | n.d. | - | 1.93 | 0.32 | n.d. | - | n.d. | - | n.d. | - | ||
| 913 | 19.72 | 2-Heptenal | 1.17 | 0.05 | 1.72 | 0.09 | 5.21 | 0.57 | 8.29 | 0.77 | 1.54 | 0.00 | 5.44 | 0.12 | 1.11 | 0.02 | ||
| 1104 | 21.67 | Nonanal | n.d. | - | 1.20 | 0.14 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 1013 | 22.53 | 2-Octenal | 1.49 | 0.02 | n.d. | - | n.d. | - | 0.95 | 0.00 | n.d. | - | n.d. | - | n.d. | - | ||
| 921 | 24.01 | 2,4-Heptadienal | 8.05 | 0.11 | n.d. | - | 2.31 | 0.19 | 1.37 | 0.20 | n.d. | - | 1.24 | 0.02 | n.d. | - | ||
| 982 | 24.77 | Benzaldehyde | 1.45 | 0.18 | n.d. | - | 1.90 | 1.67 | 1.55 | 0.31 | 0.43 | 0.10 | 8.46 | 3.09 | n.d. | - | ||
| 1174 | 28.04 | 3,7-Dimethyl-2,6-octadienal | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 1.30 | 0.07 | n.d. | - | ||
| Total | 19.73 | 10.43 | 21.41 | 21.66 | 17.61 | 20.48 | 2.92 | |||||||||||
| 487 | 2.63 | Acetic acid-methyl ester | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 586 | 3.33 | Acetic acid-ethyl ester | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 686 | 5.35 | Acetic acid-propyl ester | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 721 | 6.77 | Acetic acid-2-methyl-propyl ester | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 785 | 9.76 | Acetic acid-buthyl ester | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 820 | 12.27 | 1-Butanol-3-methyl acetate | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 992 | 19.62 | 3-Hexen-1-ol-acetate | n.d. | - | 0.66 | 0.01 | n.d. | - | n.d. | - | 0.82 | 0.08 | n.d. | - | n.d. | - | ||
| 1183 | 22.24 | Butanoic acid-hexyl ester | n.d. | - | 0.53 | 0.04 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| Total | n.d. | 1.19 | n.d. | n.d. | 0.82 | n.d. | n.d. | |||||||||||
| Ketones | ||||||||||||||||||
| 455 | 2.50 | 2-Propanone | 0.63 | 0.04 | 2.20 | 0.24 | 0.54 | 0.05 | 2.11 | 0.02 | 0.78 | 0.15 | 2.41 | 0.45 | n.d. | - | ||
| 1161 | 13.19 | 1-(1,3-dimethyl-3-cyclohexen-1-yl)-Ethanone | n.d. | - | n.d. | - | n.d. | - | 2.75 | 0.05 | n.d. | - | 0.89 | 0.05 | n.d. | - | ||
| 853 | 14.89 | 2-Heptanone | n.d. | - | 2.70 | 0.03 | 1.05 | 0.04 | 1.32 | 0.02 | n.d. | - | 1.45 | 0.36 | n.d. | - | ||
| 952 | 18.57 | 2-Octanone | n.d. | - | n.d. | - | 5.08 | 0.42 | 0.55 | 0.03 | n.d. | - | n.d. | - | n.d. | - | ||
| 960 | 19.99 | 6-Octen-2-one | n.d. | - | n.d. | - | 0.80 | 0.04 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 987 | 20.17 | 6-Methyl-5 hepten-2 one | 0.73 | 0.10 | 1.65 | 0.06 | 0.53 | 0.03 | 6.00 | 0.58 | 0.76 | 0.04 | 6.50 | 0.28 | n.d. | - | ||
| 960 | 21.96 | 3-Octen-2-one | n.d. | - | n.d. | - | 0.57 | 0.05 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 962 | 22.51 | Ketone | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 0.71 | 0.01 | n.d. | - | ||
| 968 | 24.67 | 3,5-Octadien-2-one | 0.59 | 0.07 | n.d. | - | 1.44 | 0.17 | 1.44 | 0.13 | n.d. | - | 1.39 | 0.20 | n.d. | - | ||
| Total | 1.94 | 6.55 | 10.01 | 14.16 | 1.54 | 13.35 | n.d. | |||||||||||
| Terpenes | ||||||||||||||||||
| 939 | 6.67 | α-Pinene | 1.35 | 0.06 | 120.21 | 0.54 | 4.27 | 0.25 | 147.07 | 1.23 | n.d. | - | 94.47 | 3.96 | 2.27 | 0.07 | ||
| 932 | 7.03 | α-Thujene | n.d. | - | 2.86 | 0.13 | n.d. | - | 9.40 | 0.18 | n.d. | - | 2.16 | 0.11 | n.d. | - | ||
| 961 | 8.67 | Camphene | n.d. | - | 1.69 | 0.15 | n.d. | - | 3.04 | 0.02 | n.d. | - | 7.45 | 0.26 | n.d. | - | ||
| 989 | 10.75 | β-Pinene | 0.70 | 0.00 | 37.67 | 1.33 | 1.30 | 0.14 | 33.28 | 0.36 | n.d. | - | 21.91 | 0.34 | 0.87 | 0.01 | ||
| 985 | 11.66 | Sabinene | n.d. | - | 1.64 | 0.13 | n.d. | - | 0.71 | 0.05 | n.d. | - | n.d. | - | n.d. | - | ||
| 879 | 11.74 | 2,4(10)-Thujadien | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 1017 | 12.99 | δ-3-Carene | n.d. | - | 48.70 | 4.87 | n.d. | - | 3.82 | 0.10 | n.d. | - | 6.63 | 0.99 | n.d. | - | ||
| 1015 | 13.81 | α-Phellandrene | n.d. | - | 7.37 | 0.11 | n.d. | - | 2.59 | 0.40 | n.d. | - | 3.70 | 0.60 | n.d. | - | ||
| 991 | 14.24 | β-Myrcene | 13.88 | 2.66 | 429.64 | 5.70 | 10.12 | 0.33 | 344.78 | 5.22 | n.d. | - | 74.69 | 5.07 | 10.65 | 0.30 | ||
| 1026 | 14.44 | α-Terpinene | n.d. | - | 4.29 | 0.26 | n.d. | - | 2.35 | 0.19 | n.d. | - | 2.95 | 0.49 | n.d. | - | ||
| 1038 | 15.31 | Limonene | 2.38 | 0.50 | 20.56 | 0.29 | 2.40 | 0.15 | 50.09 | 1.95 | n.d. | - | 23.56 | 1.63 | 5.53 | 0.46 | ||
| 1045 | 15.49 | Eucalyptol | n.d. | - | 3.13 | 0.02 | 0.41 | 0.06 | 15.41 | 0.72 | 0.56 | 0.09 | 17.91 | 0.72 | n.d. | - | ||
| 946 | 15.61 | β-Phellandrene | n.d. | - | 20.96 | 0.14 | n.d. | - | 7.16 | 0.27 | n.d. | - | 13.75 | 0.51 | n.d. | - | ||
| 976 | 17.05 | Cis-ocimene | n.d. | - | 19.76 | 0.13 | n.d. | - | 5.45 | 0.45 | n.d. | - | 7.22 | 0.43 | n.d. | - | ||
| 1066 | 17.15 | γ-Terpinene | n.d. | - | 4.77 | 0.03 | n.d. | - | 7.17 | 0.43 | n.d. | - | 4.59 | 0.24 | n.d. | - | ||
| Terpenes | ||||||||||||||||||
| 1000 | 17.24 | Terpene | 0.87 | 0.01 | 1.88 | 0.14 | n.d. | - | n.d. | - | n.d. | - | 1.30 | 0.17 | n.d. | - | ||
| 1029 | 17.60 | β-Ocimene | 4.44 | 0.07 | 217.33 | 2.36 | 2.42 | 0.28 | 40.93 | 2.46 | 0.88 | 0.01 | 24.18 | 1.39 | 2.91 | 0.27 | ||
| 1034 | 18.01 | p-Cymene | n.d. | - | 10.17 | 0.39 | 0.66 | 0.05 | 43.02 | 2.52 | 0.66 | 0.27 | 13.51 | 0.89 | n.d. | - | ||
| 1094 | 18.43 | α-Terpinolene | 3.55 | 0.19 | 249.23 | 0.57 | 0.76 | 0.07 | 52.02 | 3.15 | n.d. | - | 16.01 | 1.06 | 1.00 | 0.07 | ||
| 1177 | 22.74 | Para-cymenyl | 1.81 | 0.11 | 47.64 | 0.55 | 0.56 | 0.20 | 7.84 | 0.51 | 1.07 | 0.02 | 7.16 | 0.93 | n.d. | - | ||
| 1136 | 23.01 | Terpene | n.d. | - | 1.67 | 0.11 | n.d. | - | 0.53 | 0.06 | n.d. | - | n.d. | - | n.d. | - | ||
| 1083 | 23.35 | 4,8-Epoxy-p-menth-1-ene | n.d. | - | 5.65 | 0.01 | n.d. | - | 2.49 | 0.35 | n.d. | - | n.d. | - | n.d. | - | ||
| 1164 | 23.48 | Linalool oxide | 0.70 | 0.01 | 1.37 | 0.40 | n.d. | - | 2.96 | 0.25 | n.d. | - | n.d. | - | n.d. | - | ||
| 1221 | 23.68 | α-Ylangene | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 1082 | 25.29 | β-Linalool | n.d. | - | 6.35 | 0.07 | n.d. | - | 3.98 | 0.45 | n.d. | - | 4.90 | 0.14 | n.d. | - | ||
| 1494 | 25.75 | γ-Caryophyllene | 8.60 | 1.21 | 1.63 | 0.09 | 0.57 | 0.00 | 5.30 | 0.59 | 1.23 | 0.05 | 8.86 | 1.07 | n.d. | - | ||
| 1430 | 26.03 | α-Bergamotene | 6.78 | 1.09 | 1.06 | 0.24 | 0.53 | 0.03 | 11.82 | 1.57 | 2.94 | 0.11 | 19.89 | 3.59 | n.d. | - | ||
| 1456 | 26.12 | α-Guaiene | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 1.08 | 0.19 | n.d. | - | ||
| 1494 | 26.23 | Trans-caryophyllene | 78.99 | 10.43 | 39.18 | 2.69 | 4.72 | 0.14 | 92.75 | 9.99 | 15.78 | 0.51 | 228.18 | 33.12 | 1.62 | 0.28 | ||
| 1209 | 26.40 | 4-Terpineol | n.d. | - | 2.07 | 0.13 | n.d. | - | 3.74 | 0.68 | n.d. | - | 2.46 | 0.32 | n.d. | - | ||
| 1440 | 26.59 | Sesquiterpene | n.d. | - | n.d. | - | n.d. | - | 2.50 | 0.02 | n.d. | - | 2.80 | 1.76 | n.d. | - | ||
| 1386 | 27.21 | Sesquiterpene | 1.73 | 0.24 | n.d. | - | n.d. | - | 6.03 | 0.75 | 1.56 | 0.03 | 7.09 | 1.10 | n.d. | - | ||
| 1131 | 27.47 | Trans-pinocarveol | n.d. | - | 2.74 | 0.03 | n.d. | - | 8.40 | 0.80 | 0.85 | 0.10 | 2.41 | 0.17 | n.d. | - | ||
| 1482 | 27.73 | α-Humulene | 31.19 | 5.31 | 7.35 | 0.58 | 1.28 | 0.04 | 27.08 | 3.69 | 5.27 | 0.05 | 68.14 | 12.59 | n.d. | - | ||
| 1189 | 28.13 | 1,8-Menthadien-4-ol | 2.13 | 0.13 | 15.23 | 1.04 | 1.44 | 0.81 | 12.22 | 1.05 | 2.44 | 0.08 | 19.06 | 0.12 | n.d. | - | ||
| 1209 | 28.32 | α-Terpineol | n.d. | - | 2.13 | 0.19 | n.d. | - | 3.26 | 0.03 | 0.76 | 0.12 | 3.59 | 1.20 | n.d. | - | ||
| 1189 | 28.40 | Borneol | n.d. | - | n.d. | - | n.d. | - | 1.13 | 0.09 | n.d. | - | n.d. | - | n.d. | - | ||
| 1490 | 28.65 | δ-Guaiene | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 1519 | 28.72 | β-Selinene | 6.81 | 1.46 | 0.90 | 0.15 | n.d. | - | 8.70 | 1.17 | 3.03 | 0.03 | 13.72 | 2.84 | n.d. | - | ||
| 1522 | 28.82 | α-Selinene | 3.53 | 0.59 | 1.05 | 0.12 | n.d. | - | 5.44 | 0.74 | 1.81 | 0.05 | 9.48 | 1.82 | n.d. | - | ||
| 1474 | 28.98 | Sesquiterpene | 1.60 | 0.24 | n.d. | - | n.d. | - | 1.01 | 0.15 | 0.58 | 0.04 | 2.13 | 0.41 | n.d. | - | ||
| 1190 | 29.03 | Carvone | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 0.79 | 0.14 | ||
| 1507 | 29.86 | Selina-3,7(11)-diene | 5.95 | 1.25 | 1.88 | 0.33 | n.d. | - | n.d. | - | 1.86 | 0.03 | 6.99 | 1.18 | n.d. | - | ||
| 1191 | 30.13 | Myrtenol | n.d. | - | n.d. | - | n.d. | - | 1.23 | 0.16 | n.d. | - | n.d. | - | n.d. | - | ||
| 1284 | 31.17 | Cuminol | 1.51 | 0.26 | 8.56 | 1.41 | n.d. | - | 3.13 | 0.07 | 0.97 | 0.11 | 6.46 | 1.79 | n.d. | - | ||
| 1322 | 33.41 | Humulene oxide | 1.71 | 0.47 | n.d. | - | n.d. | - | 1.54 | 0.32 | 0.92 | 0.05 | 2.44 | 0.37 | n.d. | - | ||
| 1419 | 34.11 | Sesquiterpene | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 1392 | 34.86 | Eugenol | 0.76 | 0.15 | 1.18 | 0.14 | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| Total | 180.97 | 1349.52 | 31.43 | 981.37 | 43.15 | 752.82 | 25.64 | |||||||||||
| Miscellaneous | ||||||||||||||||||
| 906 | 11.03 | 3,3,6-Trimethyl-1,5-heptadiene | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 907 | 12.72 | 1,3-Dimethyl-benzene | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 1040 | 16.87 | 2-Pentyl-furan | 3.01 | 0.27 | n.d. | - | 0.56 | 0.04 | n.d. | - | n.d. | - | 1.26 | 0.12 | n.d. | - | ||
| 1020 | 18.31 | 1,2,4,-Trimethyl-benzene | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 894 | 19.54 | 2,5-Dimethyl-pyrazine | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 891 | 19.74 | 2,6-Dimethyl-pyrazine | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 1176 | 20.72 | 1,4-Bis (1-methylethyl)-benzene | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 985 | 21.89 | 2,6-Dimethyl-2,6-octadiene | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
| 1081 | 22.10 | Diethyl carbitol | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | 0.91 | 0.23 | ||
| 1039 | 22.36 | 1,3,5-Trimethylenecycloheptane | n.d. | - | 1.54 | 0.00 | n.d. | - | n.d. | - | n.d. | - | 1.15 | 0.06 | n.d. | - | ||
| 986 | 28.45 | 5-Ethyldihydro-2(3H)-furanone | 0.82 | 0.04 | 5.86 | 1.44 | 0.73 | 0.19 | 1.26 | 0.10 | n.d. | - | 5.40 | 1.36 | n.d. | - | ||
| 1190 | 30.85 | 1-Methoxy-4(1-propenyl)-benzene | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | n.d. | - | ||
RI a: retention index calculated on a Rtx-Wax (30 m × 0.25 mm × 0.25 μm f.t.); RT b: retention time (min); Average c: mean value (n = 3); Data are expressed in μg/g SD d: Standard deviatio ; n.d.: not detected.