Table 9.
Diterpene composition (relative percentage, %) of the analyzed samples.
| Species | RIexp | B. p | ________B. f________ | ____B. s_____ | ____B. b____ | B. m | B. v | A. t | A. c | ||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Sample (METXXX) | 109A | 065, 062 | 106 | 032 | BS1 | BS2 | BB1 | 038 | 048 | all | 116 | all | |
| M = 272, 121, 229 (70) | 1802.0 | - | - | - | - | 0.4–0.5 | 1.1–1.7 | 2.5 | - | - | - | - | |
| neophytadiene I | 1831.0 | - | - | 2.2 | 0.4 | 0.0–0.3 | 0.0–0.4 | 0.0–0.6 | 0.7 | 0.3 | 3.4–13 | 0.7 | 0.3–1.8 |
| neophytadiene II | 1841.0 | - | - | - | - | - | - | 0.3–0.9 | - | - | 0.0–6.8 | 1.8 | 0.9–5.3 |
| M ≥ 272,135, 122 (45) | 1852.4 | 0.2 | - | - | - | 0.5–0.5 | - | - | - | - | - | - | |
| neophytadiene III | 1866.0 | - | - | - | - | - | - | - | - | - | - | 0.3 | - |
| M = 272, 135, 91 (80) | 1881.7 | - | - | - | - | 0.0–0.5 | - | - | - | - | - | - | |
| labda-7,13,14-triene | 1891.0 | - | - | - | - | 0.0–1.0 | 0.0–0.7 | - | - | - | - | - | - |
| M ≥ 281, 95, 107 (70) | 1976.9 | - | - | - | - | - | 0.0–0.3 | - | - | - | - | - | |
| (Z)-biformene iso1 (45) | 2000.5 | - | 0.0–0.4 | 8.9 | 0.4 | 0.0–1.7 | 2.3–2.8 | 3.5–7.5 | 0.7 | - | 0.0–2.2 | - | - |
| M = 272, 73, 91 (15) | 2009.1 | - | - | - | - | 5.9–6.8 | - | - | - | 0.0–2.3 | - | - | |
| 13-epi-manoyl oxide (47) | 2016.9 | 4.3 | 0.8–1.2 | - | 0.5 | - | - | - | - | - | - | - | - |
| fusicocca-2,5-diene (42) | 2022.4 | 4.1 | 0.6–1.0 | 3.2 | 1.6 | 50.4–72.6 | 16.1–22.3 | 29.3–53.7 | 62.6 | 0.3 | 8.2–21.0 | - | - |
| (Z)-biformene iso 2 | 2027.9 | - | 0.0–0.4 | 2.1 | - | - | - | - | - | - | - | - | - |
| manoyl oxide | 2038.8 | - | - | - | 0.3 | - | - | - | - | - | - | - | - |
| M ≥ 288, 179, 81 (70) | 2044.6 | 0.4 | - | - | - | - | - | - | - | - | - | ||
| fusicocca-3,5-diene | 2060.7 | - | - | - | - | 0.0–0.2 | 0.0–0.4 | 1.1 | - | - | - | - | |
| M ≥ 272, 95, 81 (45) | 2066.8 | - | - | - | - | 0.0–3.2 | - | - | - | - | - | ||
| (−)-kaur-16-ene (43) | 2071.6 | - | - | - | - | - | - | - | - | - | 6.7 | 0.0–1.2 | |
| M ≥ 270, 69, 105 (80) | 2103.1 | - | - | - | - | - | 0.9 | - | - | - | - | ||
| M> = 278, 71, 95 (85) | 2110.5 | - | - | - | 0.7 | 0.0–0.5 | 0.0–1.1 | 0.6 | - | 0.0–8.9 | 0.8 | 0.3–0.8 | |
| (12Z)-abienol (46) | 2196.6 | 10.7 | - | - | - | - | - | - | - | - | - | - | - |
| M ≥ 270, 105, 119 (90) | 2212.0 | - | - | - | - | - | 0.0–2.6 | - | - | - | - | - | - |
| M = 288, 95, 107(80) | 2256.5 | - | - | - | - | - | 0.0–1.6 | - | - | - | - | - | - |
| M ≥ 286, 95, 107 (90) | 2294.0 | - | - | - | - | - | 0.0–4.3 | - | - | - | - | - | - |
| M ≥ 341, 95, 147 (90) | 2294.6 | 1.1 | - | - | - | - | - | - | - | - | - | - | - |
| M ≥ 286, 79, 91 (95) | 2310.2 | - | - | - | - | - | 0.0–5.1 | - | - | - | - | - | - |
| M ≥ 286, 95, 119 (90) | 2321.8 | - | - | - | - | - | 0.0–8.0 | - | - | - | - | - | - |
| M = 286, 81, 95 (85) | 2325.3 | - | - | - | - | 0.0-0.3 | - | - | - | - | - | - | 0.0–0.6 |
| M ≥ 286, 95, 243 (80) | 2339.9 | - | - | - | - | - | 0.0–3.5 | - | - | - | - | 2.5 | 0.0–0.2 |
| M ≥ 355, 83, 286 (90) | 2353.9 | 1.1 | - | - | - | - | - | - | - | - | - | - | - |
| M ≥ 286, 91, 243 (85) | 2355.6 | - | - | - | - | - | 0.0–2.0 | - | - | - | - | - | - |
| kaur-16-en-19-ol (44) | 2390.7 | - | - | - | - | - | - | - | - | - | - | 7.5 | 0.0–1.5 |
| M ≥ 288, 137, 19 (55) | 2402.9 | - | - | - | - | 0.0–0.6 | 3.8–5.5 | - | - | - | - | - | - |
| M ≥ 286, 121, 79 (85) | 2405.3 | 12.9 | - | - | - | - | - | - | - | - | - | - | - |
| M ≥ 286,95, 107 (50) | 2408.7 | - | - | - | - | 0.0–0.5 | - | - | - | - | - | - | - |
| M ≥ 286, 55, 95 (95) | 2413.5 | - | - | - | - | - | 1.7–3.9 | - | - | - | - | - | - |
| M ≥ 286,137, 95 (80) | 2487.2 | - | - | - | - | - | 1.4–6.7 | - | - | - | - | - | - |
| determined diterpene | 19.1 | 2.1–2.2 | 16.4 | 3.2 | 50.4–74.7 | 18.4–26.3 | 34.6–60.8 | 65.1 | 0.6 | 20.5–34 | 17.0 | 1.3–7.1 | |
| undetermined diterpene | 15.5 | - | - | 0.7 | 11.1–29.7 | 6.9–10.4 | 2.7–7.1 | 4.0 | - | 0.0–11.1 | 3.2 | 0.3–1.2 | |
B. p: Bazzania parisii, B. f: B. francana, B. s: B. serrifolia, B. b: B. bernieri, B. m: B. marginata, B. v: B. vittata, A. t: Acromastigum tenax, A. c: A. caledonicum.