Table 4.
Solvent | Parameters | L1 | 1 | 2 | 3 | 4 | 5 | 6 | 7 |
---|---|---|---|---|---|---|---|---|---|
DMF | Gradx | 30,664 | 212,755 | 221,420 | 233,883 | 40,170 | 766,539 | 38,980 | 3542 |
R2 | 0.9991 | 0.9989 | 0.9919 | 0.9994 | 0.9990 | 0.9989 | 0.9883 | 0.9952 | |
Φ | 0.0042 | 0.0293 | 0.0305 | 0.0322 | 0.0055 | 0.1057 | 0.0054 | 0.0005 | |
DMSO | Grad | 138,805 | 319,677 | 281,248 | 95,396 | 265,597 | 829,585 | 126,016 | 71,006 |
R2 | 0.9986 | 0.9900 | 0.9996 | 0.9916 | 0.9972 | 0.9977 | 0.9920 | 0.9939 | |
Φx | 0.0205 | 0.0473 | 0.0416 | 0.0141 | 0.0393 | 0.1227 | 0.0186 | 0.0105 |
a Gradx is the gradient of the compounds from the plot of integrated fluorescence intensity vs absorbance, R2 is the root-mean-square, Φx is the fluorescence quantum yield of the compounds. The Grad and R2 values of l-Tryptophan in ultrapure water are 1,249,037 and 0.9992.