Table 1.
Pos. | 1 | 2 | ||||
---|---|---|---|---|---|---|
δCa, Mult. | δHb (J in Hz) | HMBC | δCc Mult. | δHd (J in Hz) | HMBC | |
1 | 134.0, qC | 126.6, qC | ||||
2 | 112.8, CH | 6.90, s | 1, 3, 4, 4a, 10b | 112.8, CH | 6.93, s | 1, 3, 4, 10a, 10b, 12 |
3 | 153.8, qC | 147.8, qC | ||||
4 | 128.0, qC | 140.6, qC | ||||
4a | 147.0, qC | 138.8, qC | ||||
6 | 164.4, qC | 164.8, qC | ||||
6a | 98.9, qC | 98.2, qC | ||||
7 | 165.0, qC | 165.0, qC | ||||
8 | 99.5, CH | 6.60, d (2.0) | 7, 6a, 10a | 101.3, CH | 6.46, d (2.0) | 6a, 9, 10 |
9 | 166.7, qC | 165.3, qC | ||||
10 | 104.2, CH | 7.28, d (2.0) | 6a, 9, 10a | 104.9, CH | 7.37, d (2.0) | 6a, 8, 9, 10b |
10a | 137.9, qC | 132.8, qC | ||||
10b | 111.0, qC | 111.2, qC | ||||
11 | 55.4, CH3 | 3.96, s | 9 | 55.7, CH3 | 3.67, s | 3 |
12 | 55.2, CH3 | 3.67, s | 3 | 24.5, CH3 | 2.75, s | 1, 2, 10, 10a |
13 | 24.8, CH3 | 2.78, s | 1, 2 | |||
1′ | 105.4, qC | |||||
2′ | 195.9, qC | |||||
2′a | 117.4, qC | |||||
3′ | 139.8, qC | |||||
4′ | 123.8, CH | 6.88, d (7.8) | 5′, 6′, 7′ | |||
5′ | 137.7, CH | 7.45, t (7.8) | 4′, 6′a | |||
6′ | 109.8, CH | 6.72, d (7.8) | 2′a, 5′ | |||
6′a | 170.0, qC | |||||
7′ | 16.7, CH3 | 2.53, s | 2′a, 3′, 4′ | |||
8′ | 19.4, CH3 | 1.80, s | 1′, 2′ | |||
OH-7 | 11.89, s | 7, 8 | 11.95, s | 6a, 7, 8 |
a Recorded at 100 MHz in acetone-d6; b Recorded at 400 MHz in acetone-d6; c Recorded at 150 MHz in acetone-d6; d Recorded at 600 MHz in acetone-d6.