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. 2018 Apr 24;23(5):986. doi: 10.3390/molecules23050986

Table 2.

Flavonols identified from Myrcia sp. leaves extracts.

Formula [M − H] Theoretical Mass [M − H] m/z Experimental Mass [M − H] m/z ∆m (ppm) MS/MS Fragments m/z Compound Identification Myrcia Species
C15H9O7 301.0348 301.0348 0.01 257, 179, 151 quercetin Mf Mb
C15H9O8 317.0303 317.0304 −0.32 299, 179, 151, 137, 107 myricetin Mb Mg Mf
C20H17O11 433.0768 433.0765 0.69 300, 271, 151, quercetin–3-O-β-d-xylopyranoside Mf Mb
C21H19O11 447.0927 447.0932 −0.28 316, 287, 271, 179 quercetin-3-O-β-rhamnoside Mf Mg Mb
C20H17O12 449.0718 449.0720 −1.12 316, 271,179 myricetin-3-O-arabinoside Mf Mg
C21H19O12 463.0877 463.0880 −0.65 317, 271, 179 myricetin-3-O-rhamnoside Mf Mb Mg
C21H19O13 479.0821 479.0821 0.01 316, 271, 179, 151 myricetin-3-O-β-glucoside Mf Mg
C27H21O15 585.0886 585.0877 1.54 433, 301, 191 Quercetin-O-(O-galloyl)pentoside Mf Mb
C27H21O16 601.0835 601.0823 2.00 449, 316, 271, 179 Myricetin-O-(O-galloyl)arabinoside Mf Mb
C28H23O16 615.0947 615.0981 0.98 463, 317, 301, 179, 151 myricetin rhamnopyranoside Mf Mb Mg
C28H23O17 631.0930 631.0928 0.32 479, 316, 191, 169, 151 Myricetin galloyl galactoside Mf Mg
C28H31O17 639.1567 639.1553 2.19 447, 300, 191 quercetin-3-O-galloyldeoxipentose Mb
C28H31O18 655.1516 655.1510 0.92 463, 316, 191 myricetin galloyl rhamnopyranoside Mb Mf Mg