. 2018 May 17;23(5):1204. doi: 10.3390/molecules23051204

Table 4.

Formation constant (K_f, M⁻¹) values of CD/volatile guest inclusion complexes determined by UV-Visible spectroscopy.

Guest	Method	α-CD	β-CD	γ-CD	CRYSMEB	RAMEB	HP-β-CD
Acetophenone	BH	140 ^a	188 ^a	-	-	-	-
Allyl isothiocyanate	SD	-	36 ^b	-	-	-	-
trans-Anethole	SD	927 ^c	542 ^d	-	1039 ^c	1815 ^c	845 ^d
Anisole	BH	-	209 ^a	-	-	-	-
Anisyl alcohol	SD	-	107 ^e	-	130 ^e	125 ^e	156 ^e
Benzaldehyde	BH	102 ^a	150 ^a	-	-	-	-
Benzene	BH	29 ^a	194 ^a	-	-	-	-
Benzoic acid	BH	-	120 ^f	-	-	-	-
Benzonitrile	BH	78 ^a	170 ^a	-	-	-	-
Benzyl alcohol	BH	96 ^a	143 ^a	-	-	-	-
Benzyl alcohol	SD		63 ^e	-	57 ^e	55 ^e	54 ^e
Benzyl chloride	BH	204 ^a	280 ^a	-	-	-	-
Bromobenzene	BH	540 ^a	322 ^a	-	-	-	-
Camphor	-	3 ^g	19 ^g	-	-	-	-
Carvacrol	SD	454 ^h	2620 ^h	999 ^h	2421 ^h	3564 ^h	2154 ^h
Chlorobenzene	BH	112 ^a	196 ^a	-	-	-	-
Cineole	-	6 ^g	29 ^g	-	-	-	-
Citral	-	8 ^g	31 ^g	-	-	-	-
3,4-Dimethoxy benzaldehyde	BH	98 ⁱ	157 ⁱ	-	-	-	-
N,N-Dimethylaniline	BH	172 ^a	252 ^a	-	-	-	-
Estragole	SD	335 ^j	987 ^j	52 ^j	1584 ^j	1916 ^j	1508 ^j
Ethyl benzoate	BH	361 ^a	539 ^a	-	-	-	-
Ethyl phenyl ether	BH	171 ^a	308 ^a	-	-	-	-
N-Ethyl aniline	BH	128 ^a	217 ^a	-	-	-	-
Ethylbenzene	BH	104 ^a	389 ^a	-	-	-	-
Eugenol	BH	4.95 × 10^{4 k} 10,633 ^l	3.96 × 10^{5 k}	1.47 × 10^{5 k}	-	-	4555 ^l
	-	5 ^g	23 ^g	-	-	-	-
	SD	350 ^c	322 ^e	-	401 ^e	521 ^e	445 ^e
Fluorobenzene	BH	39 ^a	91 ^a	-	-	-	-
Furaneol	-	1.1 ^g	7 ^g	-	-	-	-
Geraniol	BH		51 ^m	-	-	-	-
Geraniol	-	9 ^g	44 ^g	-	-	-	-
4-Hydroxy-3,5-dimethoxy benzaldehyde	BH	269 ⁱ	372 ⁱ	-	-	-	-
p-Hydroxybenzaldehyde	BH		72 ⁿ	-	-	-	-
Iodobenzene	BH	1200 ^a	846 ^a	-	-	-	-
Isoeugenol	SD	178 ^c	304 ^e	-	240 ^e	547 ^e	452 ^e
Limonene	-	14 ^g	55 ^g	-	-	-	-
Menthol	-	10 ^g	35 ^g	-	-	-	-
N-Methylaniline	BH	83 ^a	131 ^a	-	-	-	-
Methyl benzoate	BH	213 ^a	317 ^a	-	-	-	-
Methyl cinnamate	-	4 ^g	20 ^g	-	-	-	-
Nerol	BH	-	26 ^m	-	-	-
Nerolidol	SD	-		-	-	-	8168 ^o
Nitrobenzene	BH	89 ^a	279 ^a	-	-	-	-
Nootkatone	-	7 ^g	32 ^g	-	-	-	-
N-Phenylacetamide	BH	103 ^a	157 ^a	-	-	-	-
Phenol	BH	40 ^a	95 ^a	-	-	-	-
Phenylacetylene	BH	86 ^a	230 ^a	-	-	-	-
Phenylamine	BH	15 ^a	86 ^a	-	-	-	-
Sabinene hydrate	SD	108 ^p	2108 ^p	708 ^p	1308 ^p	1882 ^p	772 ^p
α-Terpineol	SD	126 ^p	1143 ^p	89 ^p	1223 ^p	1287 ^p	761 ^p
Thymol	SD	107 ^h	1467 ^h	233 ^h	2386 ^h	3337 ^h	488 ^h
Toluene	BH	36 ^a	214 ^a	-	-	-	-
o-Vanillin	BH	105 ⁱ	250 ⁱ	-	-	-	-
Vanillin	BH	163 ⁱ	100 ⁿ 296 ⁱ	-	-	-	-
Vanillin	-	1.6 ^g	17 ^g	-	-	-	-
p-Vinyl guaiacol	-	2 ^g	17 ^g	-	-	-	-

CD: cyclodextrin; CRYSMEB: low methylated-β-cyclodextrin; RAMEB: randomly methylated-β-cyclodextrin; HP-β-CD: 2-hydroxypropyl-β-cyclodextrin; SBE-β-CD: sulfobutylether-β-cyclodextrin; BH: Benesi-Hildebrand; SD; spectral displacement. ^a [73], ^b [74], ^c [75], ^d [20], ^e [13], ^f [76], ^g [67], ^h [77], ⁱ [78], ^j [52], ^k [69], ^l [68], ^m [79], ⁿ [14], ^o [80], ^p [81].