Table 3.
Compounds | Absorption Transition, λmax (nm, DMF) | Band Assignments | |
---|---|---|---|
BEB | C18H20N2O4 | 277, 309, 381 | π-π*, π-π*, n-π* |
[Cu(BEB)Cl]·2H2O | C18H20N2O5Cu | 325, 345, 375, 545 | π-π*, L → M (LMCT), 2B1g → 2A1g |
[Cu(BEB)Br]·H2O | C18H22N2O6Cu | 335, 395, 565 | π-π*, L → M (LMCT), 2B1g → 2A1g |
[Cu(BEB)SCN]·2H2O | C18H22N2O6Cu | 330, 380, 547 | π-π*, L → M (LMCT), 2B1g → 2A1g |
[Cu(BEB)NO3]·3H2O | C18H22N2O6Cu | 335, 395, 570 | π-π*, L → M (LMCT), 2B1g → 2A1g |