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. 2018 Jun 29;23(7):1581. doi: 10.3390/molecules23071581

Table 3.

Absorption data, band assignments of BEB ligand and its Cu(II) complexes.

Compounds Absorption Transition, λmax (nm, DMF) Band Assignments
BEB C18H20N2O4 277, 309, 381 π-π*, π-π*, n-π*
[Cu(BEB)Cl]·2H2O C18H20N2O5Cu 325, 345, 375, 545 π-π*, L → M (LMCT), 2B1g2A1g
[Cu(BEB)Br]·H2O C18H22N2O6Cu 335, 395, 565 π-π*, L → M (LMCT), 2B1g2A1g
[Cu(BEB)SCN]·2H2O C18H22N2O6Cu 330, 380, 547 π-π*, L → M (LMCT), 2B1g2A1g
[Cu(BEB)NO3]·3H2O C18H22N2O6Cu 335, 395, 570 π-π*, L → M (LMCT), 2B1g2A1g