Skip to main content
. 2018 Aug 14;6:302. doi: 10.3389/fchem.2018.00302

Table 3.

Comparison of the light-driven oxygen evolution data catalyzed by RuCo9 and by Co3O4 under the same reaction conditionsa,b.

Catalyst TON TOF (h−1) CY (%)
RuCo9 3.2 2.3 17.2
Co3O4 0.9 0.3 12.8
a

TON, total turnover number at the final reaction time; TOF, slope of the oxygen evolution curve at the starting time; CY, total chemical yield at the final reaction time.

b

The experiments were performed in a KPi (40 mM) buffer at pH 7 with [Ru(bpy)3]2+ (1 mM) as photosensitizer, S2O82- (5 mM) as sacrificial electron acceptor, and with 13.99 μmols of Co in the form of RuCo9 or Co3O4.