Table 3.
Catalyst | TON | TOF (h−1) | CY (%) |
---|---|---|---|
RuCo9 | 3.2 | 2.3 | 17.2 |
Co3O4 | 0.9 | 0.3 | 12.8 |
TON, total turnover number at the final reaction time; TOF, slope of the oxygen evolution curve at the starting time; CY, total chemical yield at the final reaction time.
The experiments were performed in a KPi (40 mM) buffer at pH 7 with [Ru(bpy)3]2+ (1 mM) as photosensitizer, S2 (5 mM) as sacrificial electron acceptor, and with 13.99 μmols of Co in the form of RuCo9 or Co3O4.