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. Author manuscript; available in PMC: 2018 Aug 22.
Published in final edited form as: Atmos Chem Phys. 2017;17(3):2103–2162. doi: 10.5194/acp-17-2103-2017

Table 1.

Reaction rate constants of NO3+ BVOC.

Compound k(NO3+BVOC) (cm3 molecule−1 s−1)a Temperature (K) Technique/reference
Isoprene
graphic file with name nihms982684t1.jpg 		(5.94 ± 0.16)×10−13 295 RR/(Atkinson et al., 1984)
(1.30 ± 0.14)×10−12 298 DF-MS/(Benter and Schindler, 1988)
(3.03 ± 0.45)×10−12exp[−(450 ± 70)/T] 251–281 F-LIF/(Dlugokencky and Howard, 1989)
(6.52 ± 0.78)×10−13 297 F-LIF/(Dlugokencky and Howard, 1989)
(1.21 ± 0.20)×10−12 298 RR/(Barnes et al., 1990)
(7.30 ± 0.44)×10−13 298 DF-MS/(Wille et al., 1991)
(8.26 ± 0.60)×10−13 298 DF-MS/(Wille et al., 1991)
(1.07 ± 0.20)×10−12 295 PR-A/(Ellermann et al., 1992)
(6.86 ± 0.55)×10−13 298 RR/(Berndt and Boge, 1997b)
(7.3 ± 0.2)×10−13 298 F-CIMS/(Suh et al., 2001)
(6.24 ± 0.11)×10−13 295 RR/(Zhao et al., 2011b)
6.5×10−13 (Δlog k: ± 0.15) 298 IUPAC
α-pinene
graphic file with name nihms982684t2.jpg 		(5.82 ± 0.16)×10−12 295 RR/(Atkinson et al., 1984)
(1.19 ± 0.31)×10−12exp[(490 ± 70)/T] 261–383 F-LIF/(Dlugokencky and Howard, 1989)
(6.18 ± 0.94)×10−12 298 F-LIF/(Dlugokencky and Howard, 1989)
(6.56 ± 0.94)×10−12 298 RR/(Barnes et al., 1990)
(3.5 ± 1.4)×10−13exp[(841 ± 144)/T] 298–423 DF-LIF/(Martinez et al., 1998)
(5.9 ± 0.8)×10−12 298 DF-LIF/(Martinez et al., 1998)
(5.82 ± 0.56)×10−12 298 RR/(Kind et al., 1998)
(4.88 ± 0.46)×10−12 298 RR/(Stewart et al., 2013)
6.2×10−12 (Δlog k : ± 0.1) 298 IUPAC
β-pinene
graphic file with name nihms982684t3.jpg 		(2.36 ± 0.10)×10−12 295 RR/(Atkinson et al., 1984)
(2.38 ± 0.05)×10−12 296 RR/(Atkinson et al., 1988)
(1.1 ± 0.4)×10−12 298 RR/(Kotzias et al., 1989)
(2.81 ± 0.47)×10−12 298 RR/(Barnes et al., 1990)
(1.6 ± 1.5)×10−10exp[(−1248 ± 36)/T] 298–293 DF-LIF/(Martinez et al., 1998)
(2.1 ± 0.4)×10−12 298 DF-LIF/(Martinez et al., 1998)
(2.81 ± 0.56)×10−12 298 RR/(Kind et al., 1998)
2.5×10−12 (Δlog k : ± 0.12) 298 IUPAC
Sabinene
graphic file with name nihms982684t4.jpg 		(1.01 ± 0.03)×10−11 296 RR/(Atkinson et al., 1990)
(1.07 ± 0.16)×10−11 298 DF-LIF/(Martinez et al., 1999)
(2.3 ± 1.3)×10−10exp[(−940 ± 200)/T] 298–393 DF-LIF/(Martinez et al., 1999)
1.0×10−11 (Δlog k : ± 0.15) 298 IUPAC
Camphene
graphic file with name nihms982684t5.jpg 		(6.54 ± 0.16)×10−13 296 RR/(Atkinson et al., 1990)
(3.1 ± 0.5)×10−12exp[(−481 ± 55)/T] 298–433 DF-LIF/(Martinez et al., 1998)
(6.2 ± 2.1)×10−13 298 DF-LIF/(Martinez et al., 1998)
2-carene
graphic file with name nihms982684t6.jpg 		(1.87 ± 0.11)×10−11 295 RR/(Corchnoy and Atkinson, 1990)
(2.16 ± 0.36)×10−11 295 RR/(Corchnoy and Atkinson, 1990)
(1.66 ± 0.18)×10−11 298 DF-LIF/(Martínez et al., 1999)
(1.4 ± 0.7)×10−12exp[(741 ± 190)/T] 298–433 DF-LIF/(Martínez et al., 1999)
2.0×10−11 (Δlog k : ± 0.12) 298 IUPAC
3-carene
graphic file with name nihms982684t7.jpg 		(1.01 ± 0.02)×10−11 295 RR/(Atkinson et al., 1984)
(8.2 ± 1.2)×10−11 298 RR/(Barnes et al., 1990)
9.1×10−11 (Δlog k : ± 0.12) 298 IUPAC
Δ-limonene
graphic file with name nihms982684t8.jpg 		(1.31 ± 0.04)×10−11 295 RR/(Atkinson et al., 1984)
(1.12 ± 0.17)×10−11 298 RR/(Barnes et al., 1990)
(9.4 ± 0.9)×10−12 298 DF-LIF/(Martínez et al., 1999)
1.2×10−11 (Δlog k : ± 0.12) 298 IUPAC
α-phellandrene
graphic file with name nihms982684t9.jpg 		(8.52 ± 0.63)×10−11 294 RR/(Atkinson et al., 1985)
(5.98 ± 0.20)×10−11 298 RR/(Berndt et al., 1996)
(4.2 ± 1.0)×10−11 298 DF-LIF/(Martínez et al., 1999)
(1.9 ± 1.3)×10−9exp[−(1158 ± 270)/T] 298–433 DF-LIF/(Martínez et al., 1999)
7.3×10−11 (Δlog k : ± 0.15) 298 IUPAC
β-phellandrene
graphic file with name nihms982684t10.jpg 		(7.96 ± 2.82)×10−12 297 RR/(Shorees et al., 1991)
α-terpinene
graphic file with name nihms982684t11.jpg 		(1.82 ± 0.07)×10−10 294 RR/(Atkinson et al., 1985)
(1.03 ± 0.06)×10−10 298 RR/(Berndt et al., 1996)
1.8×10−10 (Δlog k : ± 0.25) 298 IUPAC
γ-terpinene
graphic file with name nihms982684t12.jpg 		(2.94 ± 0.05)×10−11 294 RR/(Atkinson et al., 1985)
(2.4 ± 0.7)×10−11 298 DF-LIF/(Martínez et al., 1999)
2.9×10−11 (Δlog k : ± 0.12) 298 IUPAC
Terpinolene
graphic file with name nihms982684t13.jpg 		(9.67 ± 0.51)×10−11 295 RR/(Corchnoy and Atkinson, 1990)
(5.2 ± 0.9)×10−11 298 DF-LIF/(Martínez et al., 1999)
(6.12 ± 0.52)×10−11 298 RR/(Stewart et al., 2013)
9.7×10−11 (Δlog k : ± 0.25) 298 IUPAC
Ocimene (cis, trans)
graphic file with name nihms982684t14.jpg 		(2.23 ± 0.06)×10−11 294 RR/(Atkinson et al., 1985)
2.2×10−11 (Δlog k : ± 0.15) 298 IUPAC
Myrcene
graphic file with name nihms982684t15.jpg 		(1.06 ± 0.02)×10−11 294 RR/(Atkinson et al., 1985)
(1.28 ± 0.11)×10−11 298 DF-LIF/(Martínez et al., 1999)
(2.2± 0.2)×10−12exp[(523 ± 35)/T] 298–433 DF-LIF/(Martínez et al., 1999)
1.1×10−11 (Δlog k : ± 0.12) 298 IUPAC
α-cedrene
graphic file with name nihms982684t16.jpg 		(0.82 ± 0.30)×10−11 296 RR/(Shu and Atkinson, 1995)
α-copaene
graphic file with name nihms982684t17.jpg 		(1.6 ± 0.6)×10−11 296 RR/(Shu and Atkinson, 1995)
β-caryophyllene
graphic file with name nihms982684t18.jpg 		(1.9 ± 0.8)×10−11 296 RR/(Shu and Atkinson, 1995)
α-humulene
graphic file with name nihms982684t19.jpg 		(3.5 ± 1.3)×10−11 296 RR/(Shu and Atkinson, 1995)
Longifolene
graphic file with name nihms982684t20.jpg 		(6.8 ± 2.1)×10−13 296 RR/(Shu and Atkinson, 1995)
Isolongifolene
graphic file with name nihms982684t21.jpg 		(3.9 ± 1.6)×10−12 298 RR/(Canosa-Mas et al., 1999b)
Alloisolongifolene
graphic file with name nihms982684t22.jpg 		(1.4 ± 0.7)×10−12 298 RR/(Canosa-Mas et al., 1999b)
α-neoclovene
graphic file with name nihms982684t23.jpg 		(8.2 ± 4.6)×10−12 298 RR/(Canosa-Mas et al., 1999b)
2-methyl-3-buten-2-ol
graphic file with name nihms982684t24.jpg 		4.6×10−14exp[−(400 ± 35)/T] 267–400 F-A/(Rudich et al., 1996)
(1.21 ± 0.09)×10−14 298 F-A/(Rudich et al., 1996)
(2.1 ± 0.3)×10−14 294 DF-A/(Hallquist et al., 1996)
(1.55 ± 0.55)×10−14 294 RR/(Hallquist et al., 1996)
(8.7 ± 3.0)×10−14 298 RR/(Fantechi et al., 1998b)
(1.0 ± 0.2)×10−14 297 RR/(Noda et al., 2002)
(1.1 ± 0.1)×10−14 297 RR/(Noda et al., 2002)
1.2×10−14 (Δlog k : ± 0.2) 298 IUPAC
3-methyl-2-buten-1-ol
graphic file with name nihms982684t25.jpg 		(1.0 ± 0.1)×10−12 297 RR/(Noda et al., 2002)
3-methyl-3-buten-1-ol
graphic file with name nihms982684t26.jpg 		(2.7 ± 0.2)×10−13 297 RR/(Noda et al., 2002)
cis-3-hexen-1-ol
graphic file with name nihms982684t27.jpg 		(2.72 ± 0.83)×10−13 296 RR/(Atkinson et al., 1995)
(2.67 ± 0.42)×10−13 298 DF-CEAS/(Pfrang et al., 2006)
trans-3-hexen-1-ol
graphic file with name nihms982684t28.jpg 		(4.43 ± 0.91)×10−13 298 DF-CEAS/(Pfrang et al., 2006)
cis-4-hexen-1-ol
graphic file with name nihms982684t29.jpg 		(2.93 ± 0.48)×10−13 298 DF-CEAS/(Pfrang et al., 2006)
trans-2-hexen-1-ol
graphic file with name nihms982684t30.jpg 		(1.30 ± 0.24)×10−13 298 DF-CEAS/(Pfrang et al., 2006)
cis-2-hexen-1-ol
graphic file with name nihms982684t31.jpg 		(1.56 ± 0.24)×10−13 298 DF-CEAS/(Pfrang et al., 2006)
trans-2-hexenal
graphic file with name nihms982684t32.jpg 		(1.21 ± 0.44)×10−14 296 RR/(Atkinson et al., 1995)
(1.36 ± 0.29)×10−14) 295 RR/(Zhao et al., 2011b)
(4.7 ± 1.5)×10−15 294 AR/(Kerdouci et al., 2012)
4-methylenehex-5-enal
graphic file with name nihms982684t33.jpg 		(4.75 ± 0.35)×10−13 296 RR/(Baker et al., 2004)
(3Z)-4-methylhexa-3,5-dienal
graphic file with name nihms982684t34.jpg 		(2.17 ± 0.30)×10−12 296 RR/(Baker et al., 2004)
(3E)-4-methylhexa-3,5-dienal
graphic file with name nihms982684t35.jpg 		(1.75 ± 0.27)×10−12 296 RR/(Baker et al., 2004)
4-methylcyclohex-3-en-1-one
graphic file with name nihms982684t36.jpg 		(1.81 ± 0.35)×10−12 296 RR/(Baker et al., 2004)
cis-3-hexenyl acetate
graphic file with name nihms982684t37.jpg 		(2.46 ± 0.75)×10−13 296 RR/(Atkinson et al., 1995)
Methyl vinyl ketone
graphic file with name nihms982684t38.jpg 		< 1.2×10−16 298 F-A/(Rudich et al., 1996)
< 6×10−16 296 DF- RR/(Kwok et al., 1996)
(3.2 ± 0.6)×10−16 296 LIF/(Canosa-Mas et al., 1999a)
(5.0 ± 1.2)×10−16 296 RR/(Canosa-Mas et al., 1999a)
< 6×10−16 298 IUPAC
Methacrolein
graphic file with name nihms982684t39.jpg 		(4.46 ± 0.58)×10−15 296 RR/(Kwok et al., 1996)
(3.08 ± 0.18)×10−15 298 RR/(Chew et al., 1998)
(3.50 ± 0.15)×10−15 298 RR/(Chew et al., 1998)
(3.72 ± 0.47)×10−15 296 RR/(Canosa-Mas et al., 1999a)
3.4×10−15 (Δlog k : ± 0.15) 298 IUPAC
Pinonaldehyde
graphic file with name nihms982684t40.jpg 		(2.40 ± 0.38)×10−14 299 RR/(Hallquist et al., 1997a)
(6.0 ± 2.0)×10−14 300 RR/(Glasius et al., 1997)
(2.0 ± 0.9)×10−14 296 RR/(Alvarado et al., 1998)
2.0×10−14 (Δlog k : ± 0.25) 298 IUPAC
Linalool
graphic file with name nihms982684t41.jpg 		(1.12 ± 0.40)×10−11 296 RR/(Atkinson et al., 1995)
α-terpineol
graphic file with name nihms982684t42.jpg 		(1.6 ± 0.4)×10−11 297 RR/(Jones and Ham, 2008)
Sabinaketone
graphic file with name nihms982684t43.jpg 		(3.6 ± 2.3)×10−16 296 RR/(Alvarado et al., 1998)
Caronaldehyde
graphic file with name nihms982684t44.jpg 		(2.5 ± 1.1)×10−14 296 RR/(Alvarado et al., 1998)
a

Given uncertainties are those provided by the authors of the kinetic studies. The procedures used to calculate them are not detailed here, as they often differ from one study to another. Readers are referred to the original papers for more information on the uncertainties’ determination.

RR: relative rate; DF-MS: discharge flow–mass spectrometry; DF-LIF: discharge flow–laser–induced fluorescence; DF-A: discharge flow–absorption; DF-CEAS: discharge flow–cavity–enhanced absorption spectroscopy; F-LIF: flow system–laser–induced fluorescence; F-CIMS: flow system–chemical ionization mass spectrometry; F-A: flow system–absorption; PR-A: pulse radiolysis–absorption; AR: absolute rate in simulation chamber.