Table 5.
Model | Gas-phase chemistry | Isoprene + NO3 parameterization | Monoterpene + NO3 parameterization |
---|---|---|---|
CAMx v6.20 with SOAP | CB05, CB6, or SAPRC99 | No SOA from this path | NO3 SOA yields same as photooxidation (OH + ozone) yields1 |
CAMx v6.20 with 1.5-D VBS | CB05, CB6, or SAPRC99 | NO3 SOA yields same as photooxidation (OH + ozone) yields2 | NO3 SOA yields same as photooxidation (OH + ozone) yields2 |
CMAQ v5.1 cb05e51-AERO6 | CB05 with additional modification3 | Odum two-product approach based on Kroll et al. (2006) photooxidation (OH) yields3 | Odum two-product approach based on Griffin et al. (1999a) photooxidation (OH + ozone) yields4 |
CMAQ v5.1 SAPRC07tc-AERO6 | SAPRC075 with two monoter- penes: α-pinene (APIN) and other monoterpenes (TERP) | Odum two-product approach based on Kroll et al. (2006) photooxidation (OH) yields3 | Odum two-product approach based on Griffin et al. (1999a) photooxidation (OH + ozone) yields4 |
CMAQ v5.1 SAPRC07tic-AERO6i | SAPRC07tic6,7 | based on semivolatile organic nitrate from isoprene dinitrate8 | no SOA from α-pinene + NO3; SOA from other monoterpenes based on semivolatile organic nitrates8 |
EURAD-IM | RACM | Odum two-product approach 9 | Odum two-product approach 10 with T dependence11,12 |
GEOS-Chem v10-01 | GEOS-Chem v10-01 with speciated isoprene nitrates6,7 | VBS fit9,13 | VBS fit to β-pinene + NO3 experiment10,13 |
GFDL AM3 | GFDL AM3 | no SOA from this pathway | Odum two-product approach based on β-pinene + NO310,14 |
GISS-GCM II | NA (offline oxidants) | no SOA from this pathway | Odum two-product approach based on β-pinene + NO310,14 |
GLOMAP/ UKESM-1 | VOC + NO3 | Based on Kroll et al. experiments (2006), set to 3 %15 | Based on Tunved et al. (2004), set to 13 %15 |
STOCHEM-CRI | MCM | CRI species fit to MCMv3.1 simulations16,17,18 | CRI species fit to MCMv3.1 simulations 16,17,18 |
WRF-Chem v3.6.1 | MOZART-MOSAIC | no SOA from this pathway | VBS fit to β-pinene + NO3 experiment10,19 |
Appel et al. (2016).
Utembe et al. (2009).
Johnson et al. (2006).