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. 2018 Jun 16;9(32):6659–6669. doi: 10.1039/c8sc00171e

Table 2. Comparison between PARET rate parameters Inline graphic for donor and acceptor cyanine dye J-aggregates strongly coupled to SP (theory) and microcavity (experiment) modes a .

graphic file with name c8sc00171e-t66.jpg SP (theory) b Microcavity (experiment) c
graphic file with name c8sc00171e-t67.jpg (2.9–3.2 fs)–1 (34 fs)–1
graphic file with name c8sc00171e-t68.jpg (177–259 ps)–1 (603 ps)–1
graphic file with name c8sc00171e-t69.jpg (6.9–12 fs)–1 (8.5 fs)–1
graphic file with name c8sc00171e-t70.jpg (178–243 ps)–1 (228 ps)–1

aSee Sections S3.3 and S3.4 for additional details.

bRanges of the rate parameters calculated from eqn (S45), plotted in Fig. S7, and accounting for the facts that typical polariton photoluminescence experiments occur at room temperature and probe only final polariton states near the anticrossings.82

cRate parameters that were obtained from experimental fitting of a kinetic model and that describe the PARET processes for a blend of J-aggregating NK-2707 (donors) and TDBC (acceptors) cyanine dyes both strongly coupled to a microcavity mode.19