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. 2018 Jun 12;9(30):6325–6339. doi: 10.1039/c8sc01043a

Table 1. Timescales relevant for the description of organic (J-aggregate) microcavity relaxation dynamics at room temperature a .

Process Initial state(s) Final state(s) Timescale Ref.
Rabi oscillations 15–50 fs (80–300 meV) 93
Cavity leakage Cavity photon 35–100 fs 94–96
UP Dark states ∼ 50 fs 11
Vibrational relaxation Dark states LP ∼ 10 fs 99
UP ∼ 100 fs 95
Photoluminescence LP ∼ 1 fs 100
Bare exciton ∼ 1–10 ps 27, 94, 100 and 101

aIn typical organic dyes, vibrational relaxation following electronic excitation occurs on the order of 10–1000 fs.97,98