Table 1. Timescales relevant for the description of organic (J-aggregate) microcavity relaxation dynamics at room temperature a .
Process | Initial state(s) | Final state(s) | Timescale | Ref. |
Rabi oscillations | — | — | 15–50 fs (80–300 meV) | 93 |
Cavity leakage | Cavity photon | — | 35–100 fs | 94–96 |
UP | Dark states | ∼ 50 fs | 11 | |
Vibrational relaxation | Dark states | LP | ∼ 10 fs | 99 |
UP | — | ∼ 100 fs | 95 | |
Photoluminescence | LP | — | ∼ 1 fs | 100 |
Bare exciton | — | ∼ 1–10 ps | 27, 94, 100 and 101 |