Table 2.
Sample | Separation between IONPs, h [nm] | H0 = 4.2 kA/m | H0 = 13.5 kA/m | ||||||
---|---|---|---|---|---|---|---|---|---|
mNP× 1024 [T × m3] |
ξ | λI | λO |
mNP× 1024 [T × m3] |
ξ | λI | λO | ||
Cit | 0.4 (a) | 1.22 | 0.62 | 1.15 | 1.10 | 2.04 | 3.33 | 3.22 | 3.08 |
2.0 (b) | 0.93 | 2.60 | |||||||
PEG | 6.8 (c) | 1.27 | 0.64 | 1.25 | 0.64 | 1.98 | 3.23 | 3.04 | 1.55 |
12.0 (d) | 0.42 | 1.01 | |||||||
15.6 (e) | 0.32 | 0.77 |
(a) estimate from neutron scattering experiments [45]; (b) maximum size corresponding to fully extended conformation (6 covalent bonds of 0.15 nm giving δ ≈ 1 nm); (c) h = 2RG (mushroom regime, RG is the radius of gyration of the PEG molecule in solution); (d) h = dDLS-dTEM (with dDLS and dTEM—average diameters measured by DLS and TEM, respectively); (e) brush regime, evaluation by Lin and Gast [46], Equation (2).