Table 1.

List of products synthesized by PpSTSs

Enzyme	Metabolite(s)
PpSTS01	α‐copaene (1379), β‐elemene (1393), β‐copaene (1434), γ‐muurolene (1479), α‐muurolene (1503), δ‐cadinene (1523)
PpSTS03	β‐elemene (1392), γ‐cadinene (1512), δ‐cadinene (1522), α‐cadinene (1541)
PpSTS06	Bicycloelemene (1335), α‐gurjunene (1412), 9‐epi‐caryophylene (1465), bicyclosesquiphellandrene (1484) bicyclogermacrene (1500), δ‐cadinene (1522)
PpSTS08	Δ6‐protoilludene (1381)
PpSTS09	Unidentified sesquiterpene scaffold
PpSTS10	α‐cubebene (1350), cyclosativene (1373), α‐copaene (1379), β‐cubebene (1391), sativene (1402), β‐copaene (1434), sesquisabinene (1453), cadina‐1(6),4‐diene (1476), γ‐muurolene (1478), bicyclosesquiphellandrene (1485), allo‐aromadendr‐9‐en (1492), epi‐cubebol (1498), α‐muurolene (1502), cubebol (1519), δ‐cadinene (1523)
PpSTS14	Pentalenene (1345), caryophyllene (1424)
PpSTS25	Myrcene (989), linalool (1100)
PpSTS29	Unidentified sesquiterpene scaffold

Retention index of each metabolite is shown in parentheses. No products were detected from PpSTP‐7, ‐13, ‐16, ‐22 and ‐24. Mass spectra of the metabolites are provided in Fig. S4.