Table 8.
Preparation Method | Solvent | Activation Energy for Permeability (kJ mol−1) | |||||
---|---|---|---|---|---|---|---|
CO2 | CH4 | O2 | N2 | He | H2 | ||
Solution casting | ethanol | 18.5 | 30.8 | 29.5 | 34.4 | 28.0 | 27.6 |
i-propanol | 18.6 | 31.0 | 30.1 | 34.6 | 28.3 | 28.0 | |
1-butanol | 18.4 | 30.8 | 29.3 | 33.2 | 26.2 | 28.3 | |
HFIP | 21.9 | 34.5 | 31.9 | 37.9 | 31.9 | 30.7 | |
Hot press | – | 19.0 | 31.2 | 30.3 | 34.5 | 28.2 | 28.1 |