Scheme 1.
Metal‐free N‐arylation of amines. DCE=1,2‐dichloroethane, EDG=electron‐donating group, EWG=electron‐withdrawing group, HMDS=hexamethyldisilazide, TFA=trifluoroacetate, Tf=trifluoromethanesulfonyl, TMP=trimethoxyphenyl.
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