1H NMR spectra (δH 0 – 10.5 ppm) of toner
powder, PM2.5 and PM0.1 printer-emitted particles acquired
with solvent suppression and exclusion regions for residual HDO. Functional
structure are indicated from right to the left: (a) aliphatic carbon
(HCCC); (b) “allylic-analogue”
(HC-C=X); (c) oxygenated and methoxy (HC-O); (d)
olefinic (R-CH=CH-R and O-CH-O); and (e)
aromatic (HCar), The respective spectral intensities
were scaled to 100% total integral within the entire region of chemical
shift (δH 0.7–10.5 ppm; with residual water
excluded). Fo: Formate, Bo: Benzoate, La: Lactate, Su: Succinate, Acetate:, TPA:
Terephthalate.