Table 2. Focused solvent screening for selected catalysts a .
| 2 | Ar | Measured% ee |
|||||
| Anhydr. toluene | Wet toluene | MTBE | CPME | EtOAc | 2-MeTHF | ||
| ab | 2-F-4-Br-C6H3 | 90.2 | 90.2 | 86.8 | 88.6 | 77.8 | 79.0 |
| al | 2-F-4-SiMe3-C6H3 | 90.4 | 91.8 | 93.7 | 92.3 | 88.9 | 89.2 |
| am | 2-F-4-l-C6H3 | 88.8 | 88.6 | 87.1 | 87.0 | 78.1 | 80.5 |
| an | 2-F-4-Bpin-C6H3 | 87.3 | 87.8 | 89.4 | 88.7 | 83.2 | 84.9 |
aΔΔG‡ given in parentheses in kcal mol–1; MTBE = methyl tert-butyl ether; CPME = cyclopentyl methyl ether.