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. 2018 Jul 18;9(34):6922–6927. doi: 10.1039/c8sc02089b

Table 2. Focused solvent screening for selected catalysts a .

2 Ar Measured% ee
Anhydr. toluene Wet toluene MTBE CPME EtOAc 2-MeTHF
ab 2-F-4-Br-C6H3 90.2 90.2 86.8 88.6 77.8 79.0
al 2-F-4-SiMe3-C6H3 90.4 91.8 93.7 92.3 88.9 89.2
am 2-F-4-l-C6H3 88.8 88.6 87.1 87.0 78.1 80.5
an 2-F-4-Bpin-C6H3 87.3 87.8 89.4 88.7 83.2 84.9

aΔΔG given in parentheses in kcal mol–1; MTBE = methyl tert-butyl ether; CPME = cyclopentyl methyl ether.