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. Author manuscript; available in PMC: 2019 Sep 3.
Published in final edited form as: Angew Chem Int Ed Engl. 2018 Aug 10;57(36):11634–11639. doi: 10.1002/anie.201805191

Figure 5:

Figure 5:

A Model peptide variants. B Conversion of 1, 2, 3 and 4 to corresponding thioester over time (1mM peptide, 2.5 mM acac 200mM MPAA in 6M GdmCl at pH 3)