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. 2018 Jul 13;293(36):13851–13862. doi: 10.1074/jbc.RA118.003972

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© 2018 White et al.

Published under exclusive license by The American Society for Biochemistry and Molecular Biology, Inc.

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Figure 4. — SAR comparisons between the two homologous esterases based on branching and heteroatom positioning. Black, carbon; red, oxygen; yellow, sulfur. A and B, comparison of substrate classes with varying α-position branching. Overall, Rv0045c catalytic effectiveness increases with increased branching, whereas ybfF does not change. C and D, comparison of various substrate classes changing heteroatom from β-position to the γ-position. Overall, catalytic effectiveness is higher in ybfF with the heteroatom in the γ-position than for Rv0045c. Error bars, S.D.