Table 1.
Lipid layer (wavenumber) |
Assignment | Ref. No. | ||||
---|---|---|---|---|---|---|
POPC | GM1a | GlcCerb | POPC + GM1a | POPC + GlcCerb | ||
cm−1 | ||||||
3342 | 3331 | O–H, N–H stretching | (43) | |||
2962 | 2964 | 2963 | 2961 | 2961 | Asymmetric stretching –CH3 | (43, 44) |
2923 | 2927 | 2926 | 2927 | 2927 | Asymmetric stretching –CH2− | (43, 44) |
2880 | 2879 | 2879 | 2879 | 2879 | Symmetric stretching –CH3 | (43) |
2856 | 2855 | 2855 | 2856 | 2856 | Symmetric stretching –CH2− | (43, 44) |
1742 | 1731 | 1741 | 1742 | C=O stretching | (44) | |
1660 | 1664 | 1667 | 1667 | Amide I | (44, 45) | |
1547 | 1541 | Amide II | (44, 45) | |||
1468 | 1466 | 1468 | 1468 | 1469 | Scissoring bending –CH2− | (43, 44) |
1379 | 1379 | 1379 | 1376 | Scissoring bending –CH3 | (43, 44, 45) | |
1261 | 1243 | 1244 | 1251 | 1251 | PO2− asymmetric stretching | (44) |
1061 | 1065 | 1060 | 1058 | 1058 | PO2− symmetric, C–O stretching | (44) |
a GM1/sphingomyelin/cholesterol (20:40:40).
b GlcCer/sphingomyelin/cholesterol (20:40:40).