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. 2018 Jul 26;9(35):7104–7114. doi: 10.1039/c8sc01754a

Table 1. Typical grafting reactions into layered perovskites.

Phase Protonated form Intermediate Organic phase Solvent Method T t Ref.
Dion–Jacobson HLaNb2O7 (HLN) Methanol Water added Stirring R.T. 1 d 11
Ethanol Water added Stirring R.T. 7 d 11
n-Alcohol, nC = 3–6, 8, 10, 12 Water added Classical heating 80 °C 7 d 11
n-Decoxyl-HLN 2-Propanol, ethylene glycol Water added Solvothermal 80 °C 7 d 13
n-Decoxyl-HLN tert-Butyl alcohol Water added Solvothermal 80 °C 14 d 13
n-Decoxyl-HLN n-CnH2n+1PO(OH)2, 4 ≤ n ≤ 18 2-Butanone + 1% water Classical heating 80 °C 2–3 d 15
n-Decoxyl-HLN n-CH3(OCH2CH2)nOH, 1 ≤ n ≤ 4 Classical heating 80 °C 14 d 12
n-Decoxyl-HLN CF3(CF2)7C2H4OH 2-Butanone + 1% water Classical heating 80 °C 7 d 24
n-Decoxyl-HLN d-Glucopyranose 2-Butanone + 10% water Solvothermal 70 °C 3 d 14
Propoxyl-HLN CF3COOH Solvothermal 70 °C 3 d 25
Propoxyl-HLN 4-Penten-1-ol Solvothermal 80 °C 7 d 23
Methanol or propanol Water added Microwave 100 °C 1 h 17
Methoxyl-HCN n-Propanol Water added Microwave 100 °C 1 h 17
Methoxyl-HCN or propoxyl-HCN n-Pentanol Water added Microwave 120 °C 1 h 17
Methoxyl-HCN or propoxyl-HCN n-Decanol Water added Microwave 150 °C 0.5 h 17
HCa2Nb3O10 (HCaN) Methanol or ethanol Water added Solvothermal 150 °C 7 d 26
Methoxyl-HCaN n-Propanol Water added Solvothermal 150 °C 7 d 26
Propoxyl-HCaN n-Alcohol, 4 ≤ nC ≤ 18 Water added Solvothermal 150 °C 7 d 26
HSr2Nb3O10 (HSN) Methanol Water added Microwave Not-mentioned 4 h 16
Methoxyl-HSN n-Propanol Water added Microwave Not-mentioned 4 h 16
Propoxyl-HSN n-Hexanol Water added Microwave Not-mentioned 3.5 h 16
Ruddlesden–Popper H2CaTa2O7 (HCT) Methylamine-HCT Methanol Water added Solvothermal 100 °C 3 d 27
Methoxyl-HCT n-Propanol Water added Solvothermal 80 °C 7 d 27
Propoxyl-HCT n-Alcohol, nC = 6, 10 Water added Solvothermal 80 °C 7 d 27
n-Decoxyl-HCT d-Glucopyranose 2-Butanone + 10% water Solvothermal 70 °C 3 d 22
Propylamine-HCT n-Propanol Water added Microwave 110 °C 1 h 17
Propoxyl-HCT n-Alcohol, nC = 5, 10 Microwave 120 °C 1 h 17
H2La2Ti3O10 (HLT) n-Butylamine-HLT n-Propanol Water added Solvothermal 180 °C 5 d 10
Propoxyl-HLT n-Alcohol, nC = 4, 8, 10, 12 Water added Solvothermal 150 °C 5 d 10
Aurivillius H2Bi0.1Sr0.85Ta2O7 (HST) Ethylamine-HST Ethanol Water added Microwave 130 °C 2 h 19
Ethoxyl-HST 4-Pentyn-1-ol Water added Microwave 110 °C 2 h 19