Table 2. NMR data of 2 (DMSO-d6) and 2′ (CDCl3).
Position | 2 | 2′ | ||
---|---|---|---|---|
δH (J in Hz) | δC | δH (J in Hz) | δC | |
1 | 119.0 | 124.8 | ||
2 | 6.56 d (1.6) | 107.6 | 6.82 d (1.9) | 108.9 |
3 | 145.6 | 151.2 | ||
4 | 140.0 | 142.1 | ||
5 | 148.1 | 153.2 | ||
6 | 7.19 d (1.6) | 107.1 | 7.30 d (1.9) | 107.4 |
7 | 166.7 | 166.5 | ||
7-COOH | 12.74 brsa) | |||
7-COOMe | 3.80 s | 52.1 | ||
5-OCH3 | 3.84 s | 48.6 | 3.93 s | 56.28 |
4-OH | 9.62 brs | |||
4-OCH3 | 4.04 s | 61.0 | ||
1′ | 134.8 | 135.9 | ||
2′,6′ | 152.7 | 153.0 | ||
3′,5′ | 7.36 s | 106.6 | 7.37 s | 106.8 |
4′ | 128.2 | 127.3 | ||
7′ | 166.9 | 166.8 | ||
7′-COOH | 12.74 brsa) | |||
7′-COOMe | 3.95 s | 52.4 | ||
2′,6′-OCH3 | 3.77 s | 56.2 | 3.82 s | 56.30 |
a) Overlapping signals.