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. 2018 Sep 18;8:14000. doi: 10.1038/s41598-018-31901-9

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© The Author(s) 2018

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Dependence of the inverse rate of cis and trans photo effects on the potential caused by adsorption of di-4-ANEPPS at (A) 20 μM (squares) or 200 μM of AlPcS₄ (down triangles) and (B) 4 nM (up triangles) or 200 nM (circles) of AlPcS₂ in water solution. The filled symbols represent the experiments where di-4-ANEPPS was at trans side of the BLM, the open ones – at the cis side. The spline lines are best fits of the theoretical model (equations T4 and T5) to the data. (C) R_t/R_c = f(T₀) plot from the results of the fit.