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. Author manuscript; available in PMC: 2019 Sep 19.
Published in final edited form as: J Am Chem Soc. 2018 Sep 10;140(37):11777–11783. doi: 10.1021/jacs.8b07277

Figure 1.

Figure 1.

5K, 7T MCD spectra of wt-FIH(black), D201GCl(red), D201G(blue), D201E(green) and D201A(purple). A) FeII-loaded resting sites, B) FeII/αKG sites and C) FeII/αKG/CAD ternary sites. In A, B and C, the Gaussianresolved band energies and Δ5E splittings are summarized in Table 1. The arrows indicate the energies at which VTVH data were collected for each sample.