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. 2018 Aug 23;51(9):2115–2128. doi: 10.1021/acs.accounts.8b00345

Figure 2.

Figure 2

Encapsulation of ligand 1 with Zn(II)TPP leads to self-assembled structure 2. The crystal structure of 2 is displayed with CH−π interactions highlighted in green. Catalyst 3 is formed under syngas pressure in the presence of a rhodium precursor (DFT optimized structure depicted; for the chemdraw structure, see Figure 5).