Table 1.
Compd. | X | Y | Z | W | R1 | R2 | Position of C=N relative to X | m.p. (˚C) | color | time(h) | Yield (%) |
---|---|---|---|---|---|---|---|---|---|---|---|
3a | CH2 | H | H | H | H | H | 3,3΄ | >260 | ochre | 17 | 77 |
3b | CH2 | H | H | H | H | H | 3,4΄ | 248-250 | light ochre | 20 | 70 |
3c | CH2 | H | H | H | H | F | 4,4΄ | >260 | ochre | 0.5 | 99 |
3d | CH2 | H | H | H | H | F | 3,3΄ | >260 | light brown | 5 | 68 |
3e | CH2 | Cl | Et | Et | H | H | 4,4΄ | >260 | orange-yellow | 15 | 74 |
3f | CH2 | H | H | H | Bn | H | 4,4΄ | 180-182 | orange | 8 | 98 |
3g | CH2 | H | H | H | Bn | H | 3,3΄ | 204-206 | oval-yellow | 3 | 82 |
3h | O | H | H | H | H | H | 3,4΄ | >260 | canary-yellow | 28 | 91 |
3i | O | H | H | H | H | F | 4,4΄ | >260 | brown-yellow | 0.5 | 87 |
3j | O | H | H | H | Bn | H | 4,4΄ | 204-206 | dark orange | 1 | 88 |
3k | CO | H | H | H | H | H | 4,4΄ | 242-244 | yellow | 0.5 | 70 |
3l | - | - | - | - | - | - | - | >260 | brick-red | 19 | 80 |