Table 2.
1H- (600 MHz) and 13C-NMR (150 MHz) data of 1 and 2.
| Position | Compound 1 a | Compound 2 b | ||
|---|---|---|---|---|
| 13C | 1H- (J Hz) | 13C | 1H- (J Hz) | |
| 1 | 80.9 | 4.34 m | 31.5 | 2.30 m (2 H) |
| 2 | 37.0 | 2.18 d (17.6) 2.82 dd (17.6, 6.0) |
141.5 | 6.96 s |
| 3 | 175.9 | --- | 131.5 | --- |
| 4 | 83.1 | --- | 38.5 | 1.86 m (2 H) |
| 5 | 50.9 | 2.42 dd (13.6, 1.2) | 27.3 | 1.44 m, 2.14 m |
| 6 | 31.7 | 1.86 m, 1.55 m | 46.8 | --- |
| 7 | 67.4 | 3.99 m | 38.7 | --- |
| 7-OH | --- | 4.61 m | --- | --- |
| 8 | 42.2 | 2.26 m | 25.4 | 1.52 m, 1.61 m |
| 9 | 82.4 | --- | 23.8 | 1.71 m, 2.30 m |
| 9-OH | --- | 4.62 m | --- | --- |
| 10 | 101.5 | --- | 33.7 | 2.11 m, 2.30 m |
| 11 | 35.2 | 2.21 m, 1.55 m | 150.7 | --- |
| 12 | 75.4 | 3.65 m | 111.9 | 4.89 s, 4.43 s |
| 12-OH | --- | 4.41 m | --- | --- |
| 13 | 83.2 | --- | 25.9 | 0.88 s (3 H) |
| 14 | 69.3 | --- | 21.4 | 0.92 s (3 H) |
| 15 | 53.2 | 3.75 brs | 170.5 | --- |
| 16 | 24.2 | 1.86 m, 1.65 m | ||
| 17 | 33.1 | 2.42 m | ||
| 19 | 67.1 | 4.22 m | ||
| 19-OH | --- | 5.56 m | ||
| 20 | 21.6 | 2.10 m | ||
| 21 | 18.7 | 0.91 d (6.4, 3 H) | ||
| 22 | 33.7 | 1.40 m, 1.41 dd (14, 3.6) |
||
| 23 | 105.4 | --- | ||
| 24 | 148.9 | 7.11 s | ||
| 25 | 130.3 | --- | ||
| 26 | 171.2 | --- | ||
| 27 | 10.2 | 1.80 s (3H) | ||
| 29 | 22.1 | 1.04 s (3H) | ||
| 30 | 28.1 | 1.19 s (3H) | ||
Measured a in DMSO-d6, b in CD3OD.