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Molecular electrostatic potential on the 0.001 au electron density isosurface of the (BrF)n supermolecules. The maximum (VS,max) electrostatic potential (in kJ mol−1) on the central Br atom is indicated. The equivalent values for (ClF)n set of complexes are: (a) 167.3; (b) 200.7; (c) 221.1; (d) 237.1; (e) 237.1; (f) 251.8. The values of the MEP vary between −105 kJ mol−1 (red) and +295 kJ mol−1 (blue).
