Table 1.
Alkaloids identified in A. belladonna by GC–MS.
| Alkaloid | RI | M+ | MS |
|---|---|---|---|
| ismine (1) | 2288.1 | 257 (28) | 239 (20), 238 (100), 225 (7), 211 (7), 196 (9), 180 (8), 139 (8) |
| trisphaeridine (2) | 2305.0 | 223 (100) | 224 (15), 222 (38), 193 (2), 164 (15), 138 (26), 111 (14) |
| buphanisine (3) | 2447.5 | 285 (100) | 270 (34), 254 (34), 242 (12), 227 (24), 215 (85), 201 (23), 185 (22), 172 (22), 157 (33), 128 (33) |
| anhydrolycorine (4) | 2470.2 | 251 (42) | 250 (100), 220 (3), 192 (18), 163 (3), 125 (2) |
| caranine (5) | 2560.9 | 271 (59) | 270 (37), 252 (53), 240 (10), 227 (44), 226 (100), 212 (6), 181 (1) |
| 1-O-acetylcaranine (6) | 2569.6 | 313 (72) | 270 (3), 252 (100), 240 (9), 227 (41), 226 (97)181 (2) |
| 8-O-demethylmaritidine (7) | 2575.5 | 273 (100) | 256 (13), 244 (12), 230 (26), 216 (14), 201 (90), 189 (61), 175 (28), , 157 (19), 141 (11), 128 (24) |
| vittatine (8) | 2578.0 | 271 (100) | 254 (11), 242 (11), 228 (22), 214 (13), 199 (58), 187 (63), 173 (24), 157 (18), 141(13), 128 (29) |
| O-methylnorbelladine (9) | 2578.5 | 273 (-) | 166 (36), 137 (100), 122 (8), 94 (6) |
| 11,12-dehydroanhydrolycorine (10) | 2638.1 | 249 (59) | 248 (100), 218 (1),190 (26), 163 (8), 137 (1), 123 (5), 95 (13) |
| 6-methoxylbuphanidrine (11) | 2656.8 | 345 (58) | 330 (33), 298 (14), 287 (32), 259 (68), 227 (30), 181 (10), 145 (13) |
| 3-O-acetylvittatine (12) | 2690.6 | 313 (100) | 298 (1), 284 (6), 270 (27), 254 (75), 252 (61), 224 (38), 216 (60), 198 (36), 187 (36), 139 (15), 128 (33) |
| powelline (13) | 2702.7 | 301 (100) | 284 (10), 272 (14), 258 (39), 244 (24), 229 (8), 217 (7), 202 (22), 187 (23), 159 (13), 143 (11), 127 (19) |
| buphanidrine (14) | 2705.2 | 315 (100) | 300 (31), 284 (35), 272 (9), 260 (39), 245 (69), 228 (24), 215 (21), 202 (20), 187 (18), 130 (18) |
| lycorine (15) | 2722.0 | 287 (18) | 286 (10), 268 (19), 250 (16), 238 (7), 227 (78), 226 (100), 211 (6), 147 (5), 119 (3) |
| buphanamine (16) | 2726.5 | 301 (100) | 282 (21), 272 (13), 256 (22), 244 (11), 190 (7), 165 (9) |
| 1-O-acetyllycorine (17) | 2754.9 | 329 (31) | 268 (31), 250 (20), 227 (64), 226 (100), 211 (6), 192 (3), 167 (3), 147 (6) |
| 3-O-acetylpowelline (18) | 2768.7 | 343 (100) | 314 (6), 300 (25), 284 (78), 283 (24), 268 (9), 254 (21), 246 (81), 228 (39), 217 (18), 202 (6), 183 (9) |
| hippadine (19) | 2775.0 | 263 (100) | 233 (2), 205 (7), 177 (24), 150 (13), 131 (9), 111 (2), 75 (7) |
| ambelline (20) | 2814.6 | 331 (86) | 316 (8), 299 (44), 287 (100), 270 (33), 260 (76), 257 (58), 239 (52), 228 (20), 211 (62), 190 (39) |
| 6-hydroxybuphanidrine (21) | 2828.4 | 331 (44) | 314 (5), 300 (10), 282 (7), 276 (100), 261 (33), 258 (13), 243 (12), 228 (8), 217 (21), 216 (22) |
| 11-O-acetylambelline (22) | 2850.2 | 373 (100) | 314 (58), 313 (50), 282 (46), 258 (48), 255 (36), 254 (63), 241 (38), 240 (35), 218 (44) |
| undulatine (23) | 2855.2 | 331 (100) | 316 (9), 300 (9), 286 (15), 258 (33), 244 (14), 232 (17), 217 (28), 205 (60), 189 (32), 173 (30) |
| 3-O-acetylhamayne (24) | 2907.7 | 329 (3) | 300 (100), 269 (6), 240 (16), 224 (8), 212 (34), 211 (14), 199 (6), 181 (54), 167 (3), 153 (18), 128 (10) |
| crinamidine (25) | 2954.3 | 317 (59) | 300 (2), 288 (100), 258 (21), 244 (27), 230 (16), 217 (35), 203 (34), 189 (20), 173 (40), 145 (17) |
| distichamine (26) | 2984.3 | 329 (100) | 328 (25), 314 (15), 300 (9), 286 (9), 269 (5), 256 (3), 231 (20), 204 (13), 190 (5), 130 (2) |