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. 2017 May 26;22(6):863. doi: 10.3390/molecules22060863

Table 1.

1H- and 13C-Nuclear Magnetic Resonance (NMR) data (400 and 100 MHz, CD3OD) of Epicatechin Trimeric Proanthocyanidin (ETP).

Ring No. 13C 1H Ring No. 13C 1H Ring No 13C 1H
C 2 79.01 5.7, s, m C′ 2′ 105.08 3.28 (d, 3.47)
4.15 (d, 3.47)
C″ 2″ 80.44 4.39 (s)
3 72.72 4.13, d, m 3′ 67.33 3.28 (d, 3.47) 3″ 67.67 3.87–3.85 (m)
4 38.92 4.6, br, s 4′ 29.01 4.15, (d, 3.47) 4″ 30 a. 2.84 (dd, 4.6, 17.3)
b. 2.84 (dd, 4.6, 17.3)
A 5 156.90 A′ 5′ 151.2 A″ 5″ 156.16
6 98.9 6.02 (d, 2.3) 6′ 96.21 5.8 (s) 6″ 96.61 6.10 (s)
7 157.95 7′ 155.9 7″ 155.94
8 96.7 5.98 (d, 2.3) 8′ 106.87 8″ 108.9
9 154.29 9′ 151.92 9″ 151.92
10 106.55 10′ 100.09 10″ 100.19
B 11 131 B′ 11′ 119.56 B″ 11″ 133.3
12 116.86 7.32 d (1.9) 12′ 115.88 6.10 d (1.5) 12″ 115.85 7.03 (d, 1.93)
13 145.89 13′ 145.46 13″ 146.74
14 146.42 14′ 145.89 14″ 146.03
15 120.01 6.83 (d, 8.0) 15′ 116.14 6.83 (d, 8.0) 15″ 116.27 6.75 (d, 8.0)
16 121.49 7.2 (dd, 1.9, 8) 16′ 115.61 7.2 (dd, 1.9, 8) 16″ 119.56 6.73 (dd, 1.93, 8.04)