Table 3.
Label | Experimental (δ, DMSO-d6) | In Silico (δ, DMSO-d6) | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
1H-NMR | 13C-NMR | 1H-NMR | 13C-NMR | |||||||||
a | b | a | b | a | b | c | d | a | b | c | d | |
1 | --- | --- | --- | --- | --- | --- | 6.89 | 7.13 | --- | --- | --- | --- |
2 | --- | 158.05 | 159.58 | --- | --- | --- | --- | 163.58 | 166.01 | 161.77 | 158.55 | |
3 | --- | --- | --- | --- | --- | --- | --- | --- | --- | --- | --- | --- |
4 | 7.93 | 7.97 | 114.67 | 118.04 | 6.75 | 7.52 | 7.54 | 7.18 | 120.50 | 121.30 | 121.08 | 119.48 |
5 | 7.87 | --- | 140.14 | 138.70 | --- | 8.57 | 8.60 | --- | 152.59 | 148.66 | 149.48 | 152.78 |
6 | --- | 7.95 | 109.32 | 113.38 | 8.38 | --- | --- | 8.44 | 121.72 | 125.74 | 126.13 | 121.83 |
7 | 7.19 | 7.20 | 107.06 | 103.48 | 8.74 | 8.10 | 8.29 | 8.71 | 107.17 | 106.15 | 108.73 | 109.66 |
8 | --- | --- | 141.88 | 141.88 | --- | --- | --- | --- | 145.53 | 140.09 | 138.02 | 144.21 |
9 | --- | --- | 142.81 | 149.73 | --- | --- | --- | --- | 151.13 | 157.75 | 183.91 | 151.70 |
10 | 7.03 | 7.03 | --- | --- | 5.54 | 5.82 | 3.81 | 5.77 | --- | --- | --- | --- |
11 | 4.83 | 4.87 | 44.87 | 44.72 | 4.30 | 4.31 | 4.25 | 3.74 | 50.92 | 50.93 | 49.35 | 48.10 |
12 | --- | --- | 165.93 | 166.08 | --- | --- | --- | --- | 173.12 | 173.57 | 172.21 | 169.12 |
13 | 8.73 | 8.78 | --- | --- | 5.15 | 5.32 | 4.98 | 4.61 | --- | --- | --- | --- |
14 | 4.32 | 4.33 | 42.41 | 42.39 | 4.61 | 4.62 | 4.60 | 4.77 | 48.44 | 48.56 | 47.53 | 48.10 |
1′ | --- | --- | 138.77 | 134.31 | --- | --- | --- | --- | 145.57 | 144.75 | 147.96 | 147.03 |
2′ | 7.23–7.36 | 127.20 | 127.15 | 7.48 | 7.50 | 7.44 | 7.63 | 135.56 | 135.36 | 135.06 | 134.90 | |
3′ | 7.23–7.36 | 127.20 | 128.19 | 7.64 | 7.63 | 7.75 | 7.69 | 134.15 | 134.59 | 134.90 | 134.12 | |
4′ | 7.23–7.36 | 126.79 | 127.13 | 7.62 | 7.61 | 7.70 | 7.68 | 134.88 | 134.92 | 133.23 | 134.04 | |
5′ | 7.23–7.36 | 127.20 | 128.19 | 7.63 | 7.62 | 7.63 | 7.74 | 134.30 | 134.11 | 134.47 | 134.53 | |
6′ | 7.23–7.36 | 127.20 | 127.15 | 7.50 | 7.46 | 7.72 | 7.47 | 135.25 | 135.38 | 136.46 | 135.65 |