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. 2017 Mar 31;22(4):569. doi: 10.3390/molecules22040569

Table 4.

The thermodynamic parameters of formation of the TB-BSA and TB-gBSA complex; λex = 275 nm and λex = 295 nm.

TB-BSA
T (K) λex = 275 nm λex = 295 nm
ΔG ± SD (kJ∙mol−1) ΔH ± SD (J∙mol−1) ΔS ± SD (J∙mol−1∙K−1) ΔG ± SD (kJ∙mol−1) ΔH ± SD (J∙mol−1) ΔS ± SD (J∙mol−1∙K−1)
309 −28.97 ± 0.03 −24.93 ± 0.06
311 −27.88 ± 0.16 −277.69 ± 47.22 −804.21 ± 151.81 −24.95 ± 0.03 ---*) ---*)
313 −25.74 ± 0.07 −24.44 ± 0.04
TB-gBSA
T (K) λex = 275 nm λex = 295 nm
ΔG ± SD (kJ∙mol−1) ΔH ± SD (J∙mol−1) ΔS ± SD (J∙mol−1∙K−1) ΔG ± SD (kJ∙mol−1) ΔH ± SD (J∙mol−1) ΔS ± SD (J∙mol−1∙K−1)
309 −24.43 ± 0.12 −28.51 ± 0.03
311 −24.37 ± 0.12 377.87 ± 31.68 1292.58 ± 101.84 −28.60 ± 0.02 ---*) ---*)
313 −26.60 ± 0.02 −27.84 ± 0.01

SD, standard deviation; *), unable to calculate.