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. 2017 May 12;22(5):780. doi: 10.3390/molecules22050780

Scheme 26.

Scheme 26

Intramolecular C–H amination via Pd(II)/Pd(IV) catalysis with PhI(OAc)2. (a) Daugulis report on direct C(sp3)-amination (b) Chen’s C(sp3) and C(sp2)–H amination.