Table 5.
Compound No. | Concentration (ng/mL) | Freeze-Thaw Cycles | At −80 °C for a Month | Auto-Sampler for 24 h | |||
---|---|---|---|---|---|---|---|
Accuracy (%) | Precision (RSD, %) | Accuracy (%) | Precision (RSD, %) | Accuracy (%) | Precision (RSD, %) | ||
1 | 2.82 | 95.34 | 8.48 | 78.53 | 9.15 | 91.54 | 9.43 |
1.41 × 102 | 89.93 | 7.63 | 81.91 | 8.18 | 93.18 | 9.67 | |
2.82 × 103 | 95.99 | 9.33 | 99.31` | 7.91 | 93.22 | 9.13 | |
2 | 2.27 | 87.95 | 10.34 | 91.39 | 9.99 | 91.98 | 10.38 |
1.14 × 102 | 89.34 | 12.09 | 93.27 | 10.28 | 94.45 | 11.00 | |
1.14 × 103 | 91.16 | 10.94 | 99.78 | 6.59 | 101.03 | 7.38 | |
3 | 1.87 | 81.94 | 10.75 | 92.63 | 6.63 | 103.05 | 6.97 |
9.35 × 10 | 93.87 | 11.50 | 92.66 | 8.69 | 97.09 | 8.24 | |
9.35 × 102 | 99.63 | 6.13 | 99.18 | 9.17 | 98.48 | 8.19 | |
4 | 1.77 | 95.36 | 7.04 | 89.15 | 8.01 | 87.53 | 9.17 |
8.85 × 10 | 99.37 | 15.13 | 87.63 | 11.37 | 89.79 | 12.58 | |
1.77 × 103 | 99.25 | 11.59 | 95.44 | 10.13 | 89.99 | 8.88 | |
5 | 1.82 | 90.35 | 8.19 | 75.93 | 11.30 | 75.55 | 9.48 |
9.10 × 10 | 97.59 | 11.57 | 92.26 | 6.59 | 87.63 | 5.33 | |
9.10 × 102 | 97.71 | 8.15 | 103.15 | 9.27 | 87.61 | 9.23 | |
6 | 2.11 | 87.55 | 11.68 | 81.23 | 9.69 | 80.18 | 9.17 |
1.06 × 102 | 86.19 | 8.87 | 83.34 | 11.34 | 89.91 | 8.62 | |
1.06 × 103 | 78.13 | 8.93 | 81.96 | 5.98 | 93.13 | 6.18 | |
7 | 2.22 | 68.93 | 7.52 | 79.95 | 11.97 | 81.39 | 9.74 |
1.11 × 102 | 81.54 | 8.91 | 78.18 | 8.13 | 83.57 | 8.11 | |
2.22 × 103 | 79.96 | 7.11 | 103.09 | 8.09 | 87.79 | 7.18 | |
8 | 2.14 | 71.63 | 11.88 | 85.34 | 13.09 | 94.53 | 8.81 |
1.07 × 102 | 96.15 | 7.89 | 89.92 | 7.08 | 96.97 | 6.53 | |
1.07 × 103 | 96.03 | 7.14 | 91.00 | 5.90 | 99.90 | 5.44 | |
9 | 1.81 | 90.23 | 12.08 | 87.34 | 7.12 | 91.81 | 13.13 |
9.05 × 10 | 91.52 | 10.93 | 88.16 | 7.09 | 95.58 | 10.95 | |
1.81 × 103 | 94.47 | 13.67 | 95.84 | 7.24 | 76.17 | 8.91 | |
10 | 1.85 | 90.57 | 9.14 | 88.85 | 8.96 | 76.17 | 8.91 |
9.25 × 10 | 90.78 | 11.00 | 89.93 | 6.93 | 88.00 | 13.59 | |
9.25 × 102 | 92.79 | 8.35 | 92.38 | 6.65 | 89.64 | 11.65 | |
11 | 1.82 | 89.87 | 8.79 | 85.13 | 15.53 | 83.29 | 11.94 |
9.10 × 10 | 91.34 | 7.69 | 90.03 | 9.18 | 92.23 | 10.87 | |
1.82 × 103 | 99.69 | 8.12 | 99.36 | 8.36 | 101.43 | 9.92 |