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Haliangicin biosynthesis in Haliangium ochraceum. ACD = acyl-CoA dehydrogenase, AT = acyltransferase, ACP = acyl carrier protein, KS = ketosynthases, DH = dehydratase, ER = enoyl reductase, KR = ketoreductase, OMT = O-methyltransferase, TE = metallo-β-lactamase-type thioesterase, EPO = epoxidase. AT, ACP, KS, DH, ER, KR and TE are enzymes commonly observed in PKSs; OMT and EPO are tailoring enzymes.
