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. 2018 Aug 26;8(9):661. doi: 10.3390/nano8090661

Table 1.

Summary of potential MOFs and their properties in water adsorption. Reproduced with permission from [32], Tomsk Polytechnic University, 2018.

MOFs Metals Linkers Surface area (m2·g–1) Pore diameter (nm) Pore volume (cm3·g–1) Uptake* (cm3·g–1) references
CAU-10 Al 1,3-H2BDC 635 0.7 0.25 0.31 [39]
CAU-10-H Al 1,3-H2BDC 635 n.d. 0.5 0.382 [39]
CAU-10-NH2 Al 5-H2BDC-NH2 n.d. n.d. n.d. 0.19 [39]
CAU-10-NO2 Al 5-H2BDC-NO2 440 n.d. 0.18 0.15 [39]
CAU-10-OCH3 Al 5-methoxyiso-phthalic acid n.d. n.d. n.d. 0.07 [39]
CAU-10-OH Al 5- H2BDC-OH n.d. n.d. n.d. 0.27 [39]
CAU-6 Al BDC- NH2 620 n.d. 0.25 0.485 [40]
DUT-4 Al H2NDC 1360 n.d. 0.79 0.28 [41]
DUT-67 Zr H2TDC 1560 1.66/0.88 0.60 0.625 [29]
MIL-100 Cr H3BTC 1517 2.5/2.9 n.d. 0.41 [42]
MIL-100 Fe H2BDC 1549 n.d. 0.82 0.81 [41]
1917 2.5/2.9 1.0 0.77 [43]
MIL-100 Al H3BTC 1814 2.5/2.9 1.14 0.50 [43]
MIL-100 Cr H3BTC 1330 2.5/2.9 0.77 0.40 [44]
2059 2.9/3.4 1.103 1.01 [45]
3017 n.d. 1.61 1.28 [41]
3124 2.9/3.4 1.58 1.40 [46]
MIL-100-DEG Cr H3BTC 580 1.2/1.5/1.9 0.50 0.33 [44]
MIL-100-EG Cr H3BTC 710 1.2/1.5/1.9 0.47 0.43 [44]
MIL-101-NH2 Cr H2BDC 2509 <2.9/3.4 1.27 0.90 [46]
2690 <2.9/3.4 1.60 1.06 [47]
MIL-101-NO2 Cr H2BDC 2146 <2.9/3.4 1.19 1.08 [46]
1245 <2.9/3.4 0.7 0.44 [47]
MIL-101-pNH2 Cr H2BDC 2495 <2.9/3.4 1.44 1.05 [47]
MIL-101-pNO2 Cr H2BDC 2195 <2.9/3.4 1.11 0.6 [47]
MIL-101-soc Cr H4TCPT 4549 n.d. 2.1 1.95 [38]
MIL-125 Ti H2BDC 1160 0.6/1.1 0.47 0.36 [30]
MIL-125-NH2 Ti H2BDC-NH2 830 0.6/1.1 0.35 0.36 [30]
1220 0.6/1.26 0.55 0.37 [48]
MIL-53 Al H2BDC 1040 0.7-1.3 0.51 0.09 [30]
n.d. n.d. n.d. 0.09 [49]
MIL-53-NH2 Al H2BDC-NH2 940 0.7-1.3 0.37 0.05 [30]
n.d. n.d. n.d. 0.09 [49]
MIL-53-OH Al H2BDC-OH n.d. n.d. n.d. 0.40 [49]
MIL-53 Ga H2BDC 1230 0.8-2 0.47 0.05 [30]
MIL-53-NH2 Ga H2BDC-NH2 210 0.8-2 n.d. 0.02 [30]
MIL-53-(COOH)2 Fe H2BDC-(COOH)2 n.d. n.d. n.d. 0.16 [49]
MIL-68 In H2BDC 1100 0.6/1.6 0.42 0.32 [30]
MIL-68-NH2 In H2BDC-NH2 850 0.6/1.6 0.302 0.32 [30]
MOF(NDI-SEt) Zn Pyrazole ligands 888 n.d. 1.6 0.25 [50]
MOF(NDI-SO2Et) Zn Pyrazole ligands 764 n.d. <1.6 0.25 [50]
MOF(NDI-SOEt) Zn Pyrazole ligands 927 n.d. <1.6 0.30 [50]
MOF-199 Cu H3BTC 1340 n.d. 0.72 0.55 [41]
921 2.1 0.492 0.64 [51]
1270 0.9,0.6 0.62 0.49 [52]
MOF-74 Co DOT 1130 1.11 0.49 0.63 [29]
MOF-74 Mg DOT 1250 1.11 0.53 0.75 [29]
1400 1.1 0.65 0.62 [52]
MOF-74 Ni DOT 1040 1.11 0.46 0.615 [29]
639 2.3 0.362 0.48 [51]
MOF-801-P Zr Fumaric acid 990 0.74,0.56,0.48 0.45 0.450 [29]
MOF-801-SC Zr Fumaric acid 690 0.74,0.56,0.48 0.27 0.35 [29]
MOF-802 Zr PZDC 1290 0.84,0.74 0.49 0.11 [29]
MOF-804 Zr DOT 1145 0.72,0.68 0.46 0.29 [29]
MOF-805 Zr NDC-(OH)2 1230 0.95,0.86 0.48 0.415 [29]
MOF-806 Zr BPDC-(OH)2 2220 1.26,1.01 0.85 0.425 [29]
MOF-808 Zr BTC 2060 1.84 0.84 0.735 [29]
MOF-841 Zr H4MTB 1390 0.92 0.53 0.640 [29]
PIZOF-2 Zr PEDB-(OMe)2 2080 1.76 0.88 0.850 [29]
SIM-1 Zn 4-methyl-5-imidazolecarboxaldehyde 570 0.65 0.303 0.14 [30]
UiO-66 Zr H2BDC 1290 0.84,0.74 0.49 0.535 [29]
1032 0.75/1.2 0.77 0.40 [48]
1105 0.55 0.39 [53]
1160 0.6 0.52 0.37 [52]
UiO-66-1,4-Naphyl Zr 1,4-Naphyl 757 n.d. 0.42 0.26 [53]
UiO-66-2,5-(OMe)2 Zr 2,5-(OMe)2 868 n.d. 0.38 0.42 [53]
UiO-66-NH2 Zr H2BDC-NH2 1328 0.75/1.2 0.70 0.38 [48]
1123 <0.75/1.2 0.52 0.34 [53]
1040 0.6 0.57 0.37 [52]
UiO-66-NO2 Zr H2BDC-NO2 792 <0.75/1.2 0.40 0.37 [53]
UiO-67 Zr H2BPDC 2064 1.2/1.6 0.97 0.18 [48]
ZIF-8 Zn 2-MIM 1255 n.d. 0.64 0.02 [41]
1530 1.1 0.485 0.01 [30]

*Water adsorption properties measured at 298 K at nearly saturated vapor pressure (P/P0 ≈ 1), n.d. = no data. Ligand abbreviation: 1,3-H2BDC = 1,3-benzenedicarboxylic acid/1,4-Naphyl = 1,4-naphthalenedicarboxylic acid/2,5-(OMe)2 = 2,5-dimethoxy-terephthalic acid/2-MIM = 2-methylimidazole/5-H2BDC-NH2 = 5-aminoisophthalic acid/5-H2BDC-NO2 = 5-nitroisophthalic acid/5-H2BDC-OH = 5-hydroxyisophthalic acid/DEG = diethylene glycol/DOT or H2BDC-(OH)2= 2,5-dihydroxy-1,4-benzenedicarboxylic acid/EN = ethylenediamine/H2BDC = 1,4-benzenedicarboxylic acid/H2BDC-(COOH)2 = 1,2,4,5-benzenetetracarboxylic acid/H2BDC-NH2= 2-aminoterephthalic acid/H2BDC-NO2= 2-nitro-terephthalic acid/H2BDC-OH = 2-hydroxyterephthalic acid/H2BPDC = biphenyl-4,4´-dicarboxylic acid/H2BPDC-(OH)2= 3,3'-dihydroxy-4,4'-biphenyldicarboxylic acid / H2NDC-(OH)2 =1,5-dihydroxynaphthalene-2,6-dicarboxylic acid/H2-PEDB-(OMe)2= 4,4'-[(2,5-dimethoxy-1,4-phenylene)bis(ethyne-2,1-diyl)]dibenzoic acid/H2PZDC = 1H-pyrazole-3,5-dicarboxylic acid/H2TDC = thiophene-2,5-dicarboxylic acid/H3BTC = 1,3,5-benzenetricarboxylic acid/H4MTB = 4,4',4'',4'''-methanetetrayltetrabenzoicacid/H4TCPT = 3,3’’,5,5’’-tetrakis(4-carboxyphenyl)-p-terphenyl.