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Solid‐state structures of 1 and 2. Thermal ellipsoids drawn at 50 % probability; anions and most hydrogen atoms omitted for clarity. Selected data for 1: Rh1–Cnt(C2,C3) 2.033(3) Å, C2–C3 1.373(4) Å, Rh1–N101 2.116(2) Å, Rh1–C109 2.037(2) Å, Rh1–C115 2.042(2) Å; Py‐Rh‐C=C twist 16.0(2)°; for 2: Rh1–Cnt(C2,C3) 1.996(3) Å, C2–C3 1.363(5) Å, Rh1–N101 2.116(2) Å, Rh1–C109 2.042(3) Å, Rh1–C115 2.061(3) Å; Py‐Rh‐C=C twist 31.7(2)°.13
