Mn1—O1i | 2.1680 (15) | C4—H4 | 0.9300 |
Mn1—O1 | 2.1681 (15) | C4—C5 | 1.381 (3) |
Mn1—O2i | 2.1822 (15) | O4—C8 | 1.251 (3) |
Mn1—O2 | 2.1822 (15) | O5—C8 | 1.254 (2) |
Mn1—O4i | 2.1207 (16) | C5—H5 | 0.9300 |
Mn1—O4 | 2.1207 (16) | C6—C7 | 1.508 (3) |
O1—N1 | 1.351 (2) | O6—C10 | 1.262 (2) |
O1—Mn2 | 2.2113 (15) | C7—H7A | 0.9600 |
C1—H1 | 0.9300 | C7—H7B | 0.9600 |
C1—N1 | 1.341 (3) | C7—H7C | 0.9600 |
C1—C2 | 1.377 (3) | O7—C10 | 1.255 (2) |
N1—C5 | 1.341 (3) | O8—C12 | 1.290 (2) |
Mn2—O3i | 2.2404 (15) | C8—C9 | 1.510 (3) |
Mn2—O5 | 2.1062 (15) | C9—H9A | 0.9600 |
Mn2—O6 | 2.1551 (15) | C9—H9C | 0.9600 |
Mn2—O8ii | 2.2671 (14) | C9—H9B | 0.9600 |
Mn2—O10 | 2.1506 (16) | O9—C12 | 1.228 (3) |
C2—H2 | 0.9300 | C10—C11 | 1.506 (3) |
C2—C3 | 1.380 (4) | O10—H10A | 0.848 (17) |
O2—C6 | 1.250 (2) | O10—H10B | 0.829 (17) |
O3—Mn3iii | 2.2028 (15) | C11—H11A | 0.9600 |
O3—C6 | 1.278 (2) | C11—H11B | 0.9600 |
C3—H3 | 0.9300 | C11—H11C | 0.9600 |
C3—C4 | 1.380 (3) | C12—C13 | 1.509 (3) |
Mn3—O7ii | 2.1338 (15) | C13—H13A | 0.9600 |
Mn3—O7 | 2.1338 (15) | C13—H13B | 0.9600 |
Mn3—O8 | 2.2194 (14) | C13—H13C | 0.9600 |
Mn3—O8ii | 2.2194 (14) | ||
O1i—Mn1—O1 | 180.00 (7) | O7—Mn3—O7ii | 180.0 |
O1i—Mn1—O2i | 91.91 (6) | O7—Mn3—O8 | 91.58 (6) |
O1—Mn1—O2i | 88.09 (6) | O7—Mn3—O8ii | 88.43 (6) |
O1i—Mn1—O2 | 88.09 (6) | O7ii—Mn3—O8ii | 91.57 (6) |
O1—Mn1—O2 | 91.91 (6) | O7ii—Mn3—O8 | 88.43 (6) |
O2—Mn1—O2i | 180.0 | O8—Mn3—O8ii | 180.00 (5) |
O4i—Mn1—O1i | 92.47 (6) | C3—C4—H4 | 120.2 |
O4—Mn1—O1 | 92.47 (6) | C3—C4—C5 | 119.7 (2) |
O4i—Mn1—O1 | 87.53 (6) | C5—C4—H4 | 120.2 |
O4—Mn1—O1i | 87.53 (6) | C8—O4—Mn1 | 130.47 (13) |
O4i—Mn1—O2 | 91.36 (6) | C8—O5—Mn2 | 139.17 (14) |
O4—Mn1—O2 | 88.64 (6) | N1—C5—C4 | 119.5 (2) |
O4—Mn1—O2i | 91.36 (6) | N1—C5—H5 | 120.2 |
O4i—Mn1—O2i | 88.64 (6) | C4—C5—H5 | 120.2 |
O4—Mn1—O4i | 180.0 | O2—C6—O3 | 122.61 (19) |
Mn1—O1—Mn2 | 112.12 (6) | O2—C6—C7 | 118.29 (19) |
N1—O1—Mn1 | 117.31 (11) | O3—C6—C7 | 119.09 (18) |
N1—O1—Mn2 | 128.21 (11) | C10—O6—Mn2 | 129.45 (13) |
N1—C1—H1 | 120.3 | C6—C7—H7A | 109.5 |
N1—C1—C2 | 119.5 (2) | C6—C7—H7B | 109.5 |
C2—C1—H1 | 120.3 | C6—C7—H7C | 109.5 |
C1—N1—O1 | 118.17 (18) | H7A—C7—H7B | 109.5 |
C5—N1—O1 | 119.51 (16) | H7A—C7—H7C | 109.5 |
C5—N1—C1 | 122.28 (19) | H7B—C7—H7C | 109.5 |
O1—Mn2—O3i | 85.37 (6) | C10—O7—Mn3 | 135.59 (13) |
O1—Mn2—O8ii | 89.66 (5) | Mn3—O8—Mn2ii | 97.00 (6) |
O3i—Mn2—O8ii | 76.44 (5) | C12—O8—Mn2ii | 128.45 (13) |
O5—Mn2—O1 | 92.21 (6) | C12—O8—Mn3 | 134.54 (13) |
O5—Mn2—O3i | 107.68 (6) | O4—C8—O5 | 126.06 (19) |
O5—Mn2—O6 | 87.13 (6) | O4—C8—C9 | 116.96 (19) |
O5—Mn2—O8ii | 175.59 (6) | O5—C8—C9 | 116.97 (19) |
O5—Mn2—O10 | 88.66 (6) | C8—C9—H9A | 109.5 |
O6—Mn2—O1 | 176.02 (6) | C8—C9—H9C | 109.5 |
O6—Mn2—O3i | 91.08 (6) | C8—C9—H9B | 109.5 |
O6—Mn2—O8ii | 91.27 (6) | H9A—C9—H9C | 109.5 |
O10—Mn2—O1 | 88.66 (6) | H9A—C9—H9B | 109.5 |
O10—Mn2—O3i | 162.77 (6) | H9C—C9—H9B | 109.5 |
O10—Mn2—O6 | 95.25 (6) | O6—C10—C11 | 117.96 (18) |
O10—Mn2—O8ii | 87.39 (6) | O7—C10—O6 | 124.82 (19) |
C1—C2—H2 | 120.1 | O7—C10—C11 | 117.21 (18) |
C1—C2—C3 | 119.9 (2) | Mn2—O10—H10A | 106 (2) |
C3—C2—H2 | 120.1 | Mn2—O10—H10B | 124 (2) |
C6—O2—Mn1 | 123.62 (13) | H10A—O10—H10B | 113 (3) |
Mn3iii—O3—Mn2i | 98.27 (6) | C10—C11—H11A | 109.5 |
C6—O3—Mn2i | 120.04 (12) | C10—C11—H11B | 109.5 |
C6—O3—Mn3iii | 138.28 (13) | C10—C11—H11C | 109.5 |
C2—C3—H3 | 120.4 | H11A—C11—H11B | 109.5 |
C2—C3—C4 | 119.2 (2) | H11A—C11—H11C | 109.5 |
C4—C3—H3 | 120.4 | H11B—C11—H11C | 109.5 |
O3i—Mn3—O3iv | 180.00 (7) | O8—C12—C13 | 117.86 (18) |
O3i—Mn3—O8ii | 78.19 (5) | O9—C12—O8 | 123.5 (2) |
O3iv—Mn3—O8ii | 101.81 (5) | O9—C12—C13 | 118.66 (19) |
O3iv—Mn3—O8 | 78.19 (5) | C12—C13—H13A | 109.5 |
O3i—Mn3—O8 | 101.81 (5) | C12—C13—H13B | 109.5 |
O7—Mn3—O3i | 89.75 (6) | C12—C13—H13C | 109.5 |
O7ii—Mn3—O3iv | 89.75 (6) | H13A—C13—H13B | 109.5 |
O7ii—Mn3—O3i | 90.25 (6) | H13A—C13—H13C | 109.5 |
O7—Mn3—O3iv | 90.25 (6) | H13B—C13—H13C | 109.5 |