Table 2. Comparison retention time, signal-to-noise ratio(S/N) and monitored ion of drugs when hydrogen or helium is used as the carrier gas.
Drug | Carrier gas | Retention time (min) |
S/N | Monitored ion (m/z) |
---|---|---|---|---|
Acetaminophen | H2 | 16.227 | 562.29 | 151, 109, 80, 83* |
He | 17.045 | 415.15 | 109, 151, 43*, 80 | |
Acetildenafil | H2 | 41.707 | 529.77 | 127, 70, 84, 42, 112, 56, 98 |
He | 44.943 | 159.15 | 127, 70, 84, 42, 112, 56, 98 | |
Acetohexamide | H2 | 19.500 | 177.45 | 199, 184, 120*, 104, 91, 76, 64*, 51* |
He | 20.254 | 238.09 | 184, 199, 76, 121*, 43*, 139*, 91, 104 | |
Allopurinol | H2 | 22.872 | 797.93 | 136, 52, 109, 120, 67 |
He | 20.159 | 18.05 | 136, 52, 29*, 109, 67,120 | |
Aminopyrine | H2 | 19.323 | 2492.34 | 231, 97, 77, 56 |
He | 20.163 | 3188.28 | 231, 56, 97, 77 | |
Aminotadalafil | H2 | 46.301 | 131.81 | 390, 262, 204, 289, 233, 102, 169, 375, 43*, 405* |
He | 49.941 | 133.16 | 390, 204, 262, 289, 169, 233, 115*, 169, 102, 375 | |
Amitripthyline | H2 | 22.689 | 71.28 | 277, 202, 178, 152, 115, 91, 58 |
He | 23.578 | 144.76 | 277, 58, 202, 178, 115, 91, 152 | |
Amphetamine | H2 | 6.278 | 84.52 | 44, 91,65,120 |
He | 6.103 | 575.81 | 44, 91,65,120 | |
Aspirin | H2 | 8.926 | 138.22 | 120, 92, 152*, 65, 45* |
He | 9.762 | 80.64 | 92, 120, 138*, 64*, 65 | |
Atenolol | H2 | 25.113 | 12505.57 | 222, 107, 72 |
He | 25.693 | 3581.62 | 72, 107, 222 | |
Atropine | H2 | 22.698 | 1471.07 | 124, 82, 94, 289, 140, 67, 103,42 |
He | 23.598 | 1486.90 | 124, 82, 94, 289, 140, 67, 42, 103 | |
Barbital | H2 | 13.361 | 204.84 | 156, 141, 98, 112, 55, 41, 83, 69 |
He | 14.160 | 776.86 | 156, 141, 98, 55, 112, 41, 83, 69 | |
Benzbromarone | H2 | 28.290 | 204.84 | 264, 173, 279, 115, 249, 328, 145, 132*, 221 |
He | 29.169 | 6448.86 | 264, 173, 115, 279, 249, 328, 145, 63*, 221 | |
Benzocaine | H2 | 14.195 | 302.25 | 165, 120, 92, 65 |
He | 15.094 | 184.07 | 120, 165, 92, 65 | |
Betamethasone | H2 | 29.912 | 273.45 | 312, 281*, 207, 160, 122, 91, 55 |
He | 30.794 | 381.89 | 122, 312, 91, 160, 207, 41, 55, 77* | |
Bezafibrate | H2 | 26.950 | 6036.33 | 120, 139, 107, 77*, 156 |
He | 27.690 | 20.97 | 120, 139, 205*, 107, 156 | |
Bisacodyl | H2 | 29.089 | 23138.37 | 361, 319, 276, 246*, 199, 154 |
He | 29.996 | 18519.59 | 361, 276, 277*, 199, 319, 43*, 318*, 183*, 278*, 154 | |
Bromhexine | H2 | 24.672 | 240565.29 | 376, 293, 264, 112, 70, 374* |
He | 25.592 | 1374605.79 | 376, 293, 264, 305*, 112, 70 | |
Brompheniramine | H2 | 21.654 | 1070326.01 | 247, 58, 167, 72, 180, 42, 139 |
He | 22.569 | 572.47 | 247, 58, 167, 72, 180, 42, 139 | |
Bromvalerylurea | H2 | 12.902 | 18.40 | 137, 44, 100, 55, 83, 69, 120* |
He | 13.809 | 43670.57 | 137, 44, 83, 180*, 100, 55, 69 | |
Bucetin | H2 | 20.613 | 1837.10 | 223, 137, 108, 81, 53* |
He | 21.466 | 1406.13 | 137, 108, 223, 45*, 81 | |
Caffeine | H2 | 18.055 | 165.90 | 194, 109, 67 |
He | 18.878 | 283.12 | 194, 109, 67, 55*, 82* | |
Carbetapentane | H2 | 23.311 | 1995.44 | 86, 144, 115, 100, 58 |
He | 24.158 | 4056.80 | 86, 144, 115, 100, 58 | |
Carbimazole | H2 | 15.606 | 417.25 | 186, 114, 72, 81, 42, 56, 127,141 |
He | 16.519 | 1395.15 | 186, 114, 72, 81, 141, 42, 56, 127 | |
Carbinoxamine | H2 | 21.362 | 124.32 | 201, 167, 139*, 71 |
He | 22.248 | 181.70 | 201, 167, 58*, 71 | |
Carbodenafil | H2 | 43.793 | 249.58 | 84, 56, 70, 381, 452, 339, 311, 42, 113, 136* |
He | 47.202 | 96.80 | 84, 97*, 56, 70, 381, 452, 339, 311, 42, 113 | |
Carisoprodol | H2 | 18.770 | 36.02 | 245, 184, 158, 97, 83*, 69*, 55 |
He | 19.689 | 20.54 | 245, 158, 97, 184, 55, 58*, 43* | |
Chloramphenicol | H2 | 27.569 | 2199.59 | 207, 172,153, 106, 77 |
He | 28.303 | 1989.30 | 207, 153, 172, 77, 106 | |
Chlordiazepoxide | H2 | 29.238 | 170.17 | 282, 247, 220, 190, 165, 124*, 91 |
He | 30.310 | 246.65 | 282, 241*, 247, 220, 165, 190, 91 | |
Chlormezanone | H2 | 23.419 | 3689.22 | 208, 174, 152, 125, 98, 69 |
He | 24.275 | 364.87 | 152, 208, 174, 98, 125, 69 | |
Chlorpheniramine | H2 | 20.445 | 377.13 | 203, 58, 167, 72, 180, 42 |
He | 21.356 | 660.96 | 203, 58, 167, 72, 180, 42 | |
Chlorpromazine | H2 | 25.943 | 393651.65 | 318, 272, 232, 196, 86, 58 |
He | 26.863 | 1034722.73 | 318, 58, 86, 272, 232, 196 | |
Chlorpropamide | H2 | 16.426 | 413.58 | 190, 174, 127, 111, 75 |
He | 17.211 | 334.36 | 190, 111, 174, 127, 75 | |
Chlorzoxazone | H2 | 16.681 | 1126.98 | 169, 113, 78 |
He | 17.724 | 428.48 | 169, 113, 78 | |
Cimetidine | H2 | 5.722 | 101.59 | 45, 116, 55, 70, 60, 74, 42, 88* |
He | 6.651 | 305.40 | 116, 45, 55, 60, 70, 74, 42, 99* | |
Cinnarizine | H2 | 31.221 | 640.13 | 201, 117, 167, 251, 152, 91 |
He | 32.229 | 1610.46 | 201, 117, 167, 251, 152, 91 | |
Clobenzorex | H2 | 19.892 | 568.16 | 168, 127, 91, 65 |
He | 20.798 | 829.80 | 168, 127, 91, 65 | |
Clofibrate | H2 | 13.722 | 657.00 | 242, 169, 128 |
He | 14.588 | 1238.64 | 128, 242, 169 | |
Cocaine | H2 | 22.792 | 28.65 | 182, 82, 303, 105, 272, 198, 122, 51 |
He | 23.671 | 1156.47 | 182, 82, 303, 105, 272, 198, 122, 51 | |
Colchicine | H2 | 33.875 | 133.19 | 399, 371, 312, 281, 254* |
He | 35.326 | 126.04 | 312, 399, 371, 297*, 281 | |
Cortisone | H2 | 27.709 | 131.20 | 122, 300, 91, 256, 105, 77, 147, 161, 55 |
He | 28.650 | 328.98 | 122, 300, 91, 256, 161, 147, 105, 55, 77 | |
7-keto-DHEA | H2 | 28.240 | 616.13 | 302, 161, 91, 79, 105, 134, 187, 55, 41, 205 |
He | 29.196 | 3160.69 | 302, 161, 91, 79, 105, 134, 187, 55, 41, 205 | |
N-Desmethylsibutramine | H2 | 18.139 | 8921.42 | 100, 58, 44, 137, 128, 115 |
He | 18.993 | 57424.38 | 100, 58, 44, 137, 128, 115 | |
N-Didesmethylsibutramine | H2 | 18.111 | 4950.37 | 137, 115, 86 |
He | 18.989 | 2657.67 | 86, 137, 115 | |
Dexamethasone | H2 | 29.940 | 336.90 | 312, 160, 122, 91, 55 |
He | 30.655 | 478.25 | 122, 312, 160, 91, 55 | |
Dextromethorphan | H2 | 22.049 | 684403.48 | 271, 150, 214, 59, 171, 203, 128 |
He | 23.199 | 601.70 | 271, 59, 150, 214, 171, 203, 128 | |
Diazepam | H2 | 25.356 | 191.73 | 283, 256, 221, 165, 77, 51 |
He | 26.238 | 790.25 | 283, 256, 221, 165, 77, 51 | |
Dibucaine | H2 | 27.963 | 325.46 | 116, 86, 58 |
He | 28.855 | 689.64 | 116, 86, 58 | |
Diclofenac | H2 | 21.958 | 530.12 | 295, 242, 214, 179, 151 |
He | 22.816 | 979.97 | 214, 295, 242, 179, 151 | |
Dicyclomine | H2 | 21.505 | 853.46 | 86, 55 |
He | 22.375 | 5338.38 | 86, 99*, 55 | |
Diethylpropion | H2 | 12.933 | 254.89 | 100, 77, 51 |
He | 13.797 | 995.63 | 100, 77, 51 | |
Diethylstilbestrol | H2 | 23.917 | 2535.31 | 268, 239, 145, 107 |
He | 24.749 | 681.06 | 268, 107, 239, 145 | |
Dimethylsildenafil | H2 | 45.707 | 227.53 | 113, 312, 70, 84, 42, 283, 136 |
He | 49.312 | 34.59 | 113, 312, 70, 84, 42, 283, 136 | |
Diphenhydramine | H2 | 18.661 | 728.26 | 165, 58 |
He | 19.511 | 1728.75 | 165, 58 | |
Diphenylhydantoin | H2 | 24.361 | 52.21 | 180, 223, 209, 252, 104, 77, 165, 147, 51 |
He | 25.460 | 47.80 | 180, 104, 223, 209, 252, 77, 165, 51, 147 | |
Diprophylline | H2 | 24.230 | 165.79 | 254, 223, 180, 137, 109, 81, 54 |
He | 25.116 | 677.65 | 223, 254, 180, 109, 137, 81, 54 | |
Econazole | H2 | 29.123 | 312.59 | 299, 207, 125, 81, 54 |
He | 30.013 | 73.59 | 125, 81, 299, 207, 54 | |
Estradiol benzoate | H2 | 35.659 | 4236.99 | 376, 105, 77 |
He | 37.513 | 1810.32 | 376, 105, 77 | |
Estriol | H2 | 29.054 | 707.09 | 288, 160, 146, 213, 133, 172, 201, 115, 185 |
He | 30.055 | 124.67 | 288, 160, 146, 213, 133, 172, 201, 115, 185 | |
Estrone | H2 | 26.785 | 108.53 | 270, 146, 185, 213 |
He | 27.759 | 247.64 | 270, 146, 185, 213 | |
Ethinylestradiol | H2 | 27.594 | 109.99 | 213, 296, 160, 133, 145, 228, 172, 185, 115 |
He | 28.434 | 146.01 | 213, 296, 160, 133, 228, 145, 172, 185, 115 | |
Ethisterone | H2 | 27.721 | 21.79 | 124, 312, 91, 229, 245, 79, 105, 148, 286, 189, 67 |
He | 28.612 | 78.02 | 124, 312, 91, 79, 229, 245, 105, 148, 189, 67, 286 | |
Ethoxybenzamide | H2 | 14.651 | 1578.34 | 165, 150, 120, 92, 65 |
He | 15.526 | 1168.66 | 120, 92, 150, 165, 65 | |
Ethylestrenol | H2 | 24.277 | 3402.39 | 216, 241, 201, 288, 91, 270, 79, 121, 147, 105 |
He | 25.155 | 1896.52 | 216, 201, 241, 91, 79, 288, 270, 121, 147, 105 | |
Fenfluramine | H2 | 7.506 | 4201.59 | 159, 109, 72, 56* |
He | 8.267 | 8752.19 | 72, 159, 109, 44* | |
Finasteride | H2 | 33.484 | 208.98 | 372, 110, 58, 272, 357, 258, 128, 230, 72, 245 |
He | 34.822 | 168.39 | 372, 58, 110, 272, 357, 258, 128, 230, 72, 245 | |
Flavoxate | H2 | 32.588 | 218.77 | 263, 234, 147, 98 |
He | 33.827 | 681.91 | 98, 234, 147, 263 | |
Fluoxetine | H2 | 18.599 | 4320.42 | 309, 183, 162, 133, 104, 78*, 59 |
He | 19.489 | 10859.57 | 309, 183, 162, 133, 44*, 104, 59 | |
Fluoxymesterone | H2 | 29.797 | 83968.78 | 336, 279, 109, 71 |
He | 30.742 | 145899.76 | 336, 279, 71, 109 | |
Gemfibrozil | H2 | 19.329 | 1655.20 | 250, 122 |
He | 20.183 | 1357.76 | 250, 122 | |
Gendenafil | H2 | 31.414 | 520.43 | 354, 326, 339, 136, 166, 282, 43, 311, 297 |
He | 31.414 | 514.07 | 354, 326, 339, 136, 166, 282, 43, 311, 297 | |
Griseofulvin | H2 | 28.131 | 1108.72 | 352, 310, 284, 254, 214, 171, 138, 95, 69 |
He | 28.949 | 3255.28 | 352, 310, 138, 214, 284, 254, 69, 171, 95 | |
Guaifenesin | H2 | 15.537 | 1687.05 | 124,109,198,77,95,65,52,167,149 |
He | 16.375 | 3642.70 | 124, 109, 198, 77, 81, 95, 65, 52, 167 | |
Homatropine | H2 | 21.349 | 142.55 | 275, 124, 79 |
He | 22.276 | 514.41 | 124, 275, 79 | |
Homosildenafil | H2 | 48.785 | 451.37 | 113, 70, 281*, 56, 42, 207, 355, 341, 309, 253 |
He | 53.164 | 463.73 | 113, 404*, 70, 56, 42, 207, 355, 341, 309, 253 | |
Hydralazine | H2 | 19.201 | 343.84 | 160, 103, 131, 115, 89, 76, 145, 63, 50 |
He | 18.044 | 408.02 | 160, 103, 131, 115, 89, 76, 145, 63, 50 | |
Hydrocortisone | H2 | 29.064 | 187.65 | 305*, 163, 123, 91, 55 |
He | 29.931 | 458.36 | 285*, 362*, 163, 123, 91, 55 | |
Ibuprofen | H2 | 15.040 | 1090.68 | 206, 161, 117, 91, 65 |
He | 15.817 | 674.69 | 161, 206, 117, 91, 65 | |
Imidazosagatriazinone | H2 | 27.187 | 9066.54 | 312, 284, 136, 240 |
He | 27.969 | 4361.89 | 312, 284, 136, 240 | |
Indomethacin | H2 | 30.571 | 1204.53 | 139, 313*, 111, 75 |
He | 27.765 | 24.57 | 139, 357*, 111, 75 | |
Ketoprofen | H2 | 22.913 | 54.02 | 105, 177, 209, 77, 254, 45*, 194, 131, 165 |
He | 23.701 | 158.29 | 105, 77, 177, 209, 254, 51*, 194, 131, 165 | |
Lidocaine | H2 | 18.667 | 745.66 | 234, 120, 86, 58 |
He | 19.537 | 2480.92 | 86, 234, 120, 58 | |
Lorazepam | H2 | 25.073 | 80.39 | 239, 274, 302, 75, 138, 177, 111, 203, 163, 100 |
He | 25.916 | 448.96 | 239, 274, 302, 75, 138, 177, 111, 203, 163, 100 | |
Mazindol | H2 | 24.604 | 3833.98 | 266, 231, 204, 176, 128, 102, 75 |
He | 25.835 | 382.97 | 266, 231, 204, 176, 128, 102, 75 | |
Mefenamic acid | H2 | 22.179 | 2403.18 | 241, 223, 180, 152, 102* |
He | 22.732 | 186.25 | 223, 241, 180, 77*, 152 | |
Melatonin | H2 | 24.765 | 855.84 | 232, 172, 160, 145, 130, 117, 102, 89 |
He | 25.586 | 834.77 | 160, 172, 232, 145, 117, 130, 102, 89 | |
Mephenesin | H2 | 14.300 | 44.99 | 182, 108, 91 |
He | 15.027 | 2776.31 | 108, 182, 91 | |
Mephentermine | H2 | 9.224 | 3957.33 | 72, 91, 148, 56, 42, 115 |
He | 8.883 | 1232.24 | 72, 91, 148, 56, 42, 115 | |
Meprobamate | H2 | 17.741 | 904.61 | 83, 55, 43, 71, 62, 96, 114, 144, 101 |
He | 18.516 | 2359.60 | 83, 55, 71, 62, 96, 114, 144, 101, 43 | |
Methamphetamine | H2 | 6.505 | 2216.40 | 58, 91, 65, 134, 42, 115, 119* |
He | 7.195 | 3184.90 | 58, 91, 65, 56*, 134, 42, 115 | |
Methandriol | H2 | 26.350 | 74.00 | 253, 213, 271, 304, 105, 145, 286, 228, 119, 159 |
He | 27.230 | 305.46 | 253, 213, 304, 105, 145, 271, 286, 228, 119, 159 | |
Methandrostenolone | H2 | 27.749 | 76.18 | 122, 91, 161, 147, 105, 134, 77 |
He | 28.686 | 360.69 | 122, 91, 161, 147, 105, 134, 77 | |
Methaqualone | H2 | 22.282 | 1208.48 | 250, 91, 132, 65, 77, 217, 117, 50, 104* |
He | 23.192 | 3143.27 | 235*, 250, 91, 132, 65, 77, 217, 117, 50 | |
Metharbital | H2 | 12.212 | 2739.29 | 155, 112, 83, 55 |
He | 12.953 | 2922.10 | 155, 170*, 112, 83, 55 | |
Methimazole | H2 | 13.837 | 140.23 | 114, 72, 81, 42, 54, 86, 59 |
He | 14.903 | 213.63 | 114, 72, 42, 81, 54, 86, 59 | |
Methylprednisolone | H2 | 29.813 | 457.10 | 136, 91, 55* |
He | 30.677 | 1796.27 | 136, 91, 121* | |
Methyltestosterone | H2 | 27.435 | 26731.78 | 302, 229, 202, 161, 124, 91 |
He | 28.384 | 1780.50 | 302, 124, 91, 229, 202, 161 | |
Metoclopramide | H2 | 27.217 | 5295.57 | 184, 86, 58 |
He | 28.034 | 8438.34 | 86, 184, 58 | |
Metronidazole | H2 | 15.394 | 443.85 | 171, 124, 81, 53 |
He | 16.174 | 423.83 | 124, 81, 171, 53 | |
Minoxidil | H2 | 20.855 | 91.48 | 193, 164, 138, 110, 84, 67 |
He | 21.700 | 1697.28 | 193, 164, 110, 138, 84, 67 | |
Morphine | H2 | 25.421 | 592.33 | 285, 162, 42, 215, 115, 55, 65, 92, 81 |
He | 26.311 | 2101.32 | 285, 162, 42, 215, 115, 55, 65, 92, 81 | |
Nalidixic acid | H2 | 25.020 | 2964.06 | 188, 160, 132, 173, 145, 104, 232, 77 |
He | 25.602 | 4290.93 | 188, 160, 132, 173, 145, 104, 232, 77 | |
Nandrolone | H2 | 25.593 | 112.00 | 274, 215, 173*, 147, 119, 91, 67 |
He | 27.554 | 413.47 | 274, 110*, 91, 67, 119, 215, 147 | |
Naproxen | H2 | 21.384 | 479.13 | 230, 185, 170, 141, 115 |
He | 31.254 | 21.76 | 185, 230, 170, 141, 115 | |
Nifedipine | H2 | 26.652 | 2198.09 | 329, 284, 224, 268, 254, 195, 180 |
He | 27.496 | 8691.50 | 329, 284, 224, 268, 254, 195, 180 | |
Noracetildenafil | H2 | 39.756 | 143.98 | 113, 70, 42, 56, 98, 207, 311, 452, 136, 354 |
He | 42.433 | 144.95 | 113, 70, 42, 56, 98, 207, 452, 311, 136, 354 | |
Norethisterone | H2 | 27.236 | 237.22 | 298, 283*, 265 |
He | 28.102 | 855.06 | 298, 231*, 265 | |
Orphenadrine | H2 | 19.556 | 345.15 | 58, 73, 165, 178, 45 |
He | 20.419 | 1799.00 | 58, 73, 165, 178, 45 | |
Oxethazaine | H2 | 26.450 | 198.46 | 114, 86, 213, 56, 133, 72, 304 |
He | 27.281 | 289.85 | 114, 86, 56, 213, 133, 72, 304 | |
Oxymetholone | H2 | 28.615 | 8872.16 | 174, 275, 332, 43, 161, 91, 81, 71, 216, 107 |
He | 29.471 | 16927.40 | 174, 332, 275, 216, 161, 107, 43, 91, 81, 71 | |
Oxyphenbutazone | H2 | 30.658 | 324.39 | 93, 45*, 55, 69, 161, 193*, 77, 249* |
He | 31.419 | 312.73 | 93, 199*, 77, 324*, 55, 69, 161 | |
Pentazocine | H2 | 23.647 | 451.43 | 217, 202, 285, 110, 270, 70, 45, 159, 173 |
He | 24.505 | 1600.48 | 217, 202, 110, 285, 270, 70, 45, 159, 173 | |
Phenacetin | H2 | 16.184 | 2534.87 | 179, 137, 108, 80, 65, 53 |
He | 17.017 | 1248.32 | 108, 179, 137, 80, 65, 53 | |
Phenazopyridine | H2 | 23.833 | 1046.17 | 213, 108, 81, 54, 136, 97*, 184, 66, 155 |
He | 24.670 | 660.83 | 213, 108, 81, 136, 54, 184, 66, 51*, 155 | |
Phenformin | H2 | 14.011 | 274.32 | 146, 104, 91, 77, 65 |
He | 14.844 | 412.63 | 91, 146, 104, 77, 65 | |
Phenobarbital | H2 | 20.141 | 3530.71 | 204, 117, 232, 161, 146, 103, 77, 91, 174 |
He | 20.996 | 2851.29 | 204, 117, 232, 161, 146, 77, 103, 91, 174 | |
Phenolphthalein | H2 | 31.728 | 255.45 | 318, 274, 225, 181, 152, 104*, 65 |
He | 32.746 | 765.90 | 274, 318, 225, 181, 152, 121*, 65 | |
Phentermine | H2 | 6.160 | 2271.97 | 70, 91, 105, 58, 65, 115, 41, 115 |
He | 6.779 | 3375.10 | 70, 91, 105, 58, 65, 115, 41, 115 | |
Phentolamine | H2 | 26.987 | 42.57 | 199, 183, 91, 154, 77, 128, 170 |
He | 27.784 | 117.12 | 199, 183, 91, 154, 77, 128, 170 | |
Phenylbutazone | H2 | 24.709 | 3051.14 | 308, 252, 183, 152, 105, 77 |
He | 25.543 | 5464.75 | 183, 308, 252, 77, 152, 105 | |
Phenylephrine | H2 | 18.847 | 94.46 | 135, 44, 107, 179, 160, 77, 51, 91 |
He | 16.485 | 224.29 | 135, 44, 107, 179, 160, 77, 51, 91 | |
Phenylpropanolamine | H2 | 9.731 | 236.24 | 44, 77, 105, 51, 117, 91 |
He | 10.797 | 1849.14 | 44, 77, 51, 105, 117, 91 | |
Piperidenafil | H2 | 44.617 | 128.79 | 431, 459, 283, 67, 42, 84, 121, 135, 149, 215 |
He | 48.328 | 21.36 | 431, 459, 283, 67, 42, 84, 121, 135, 149, 215 | |
Pirenzepine | H2 | 31.102 | 253.75 | 351, 281, 211, 113, 70 |
He | 32.009 | 358.14 | 113, 70, 211, 351, 281 | |
Piroxicam | H2 | 16.877 | 1640.49 | 104, 76, 43, 152, 169, 118, 386*, 211, 91 |
He | 17.665 | 652.90 | 104, 152, 76, 43, 169, 118, 211, 91 | |
Prednisolone | H2 | 29.312 | 68.40 | 122, 91, 55 |
He | 30.225 | 1015.08 | 122, 91, 55 | |
Prednisone | H2 | 27.889 | 417.77 | 298, 245, 226, 186, 160, 131, 115, 91 |
He | 28.785 | 534.87 | 298, 160, 91, 245, 226, 186, 131, 115 | |
Primidone | H2 | 23.472 | 1344.44 | 146, 190, 117, 161, 103, 91, 77, 174 |
He | 24.067 | 1431.77 | 190, 146, 117, 161, 103, 91, 77, 174 | |
Probenecid | H2 | 22.941 | 295.85 | 270, 135, 199, 104, 76, 43 |
He | 23.788 | 142.22 | 270, 135, 199, 104, 76, 43 | |
Procaine | H2 | 20.737 | 341.47 | 86, 99, 120, 65, 56, 164 |
He | 21.644 | 523.45 | 86, 99, 120, 164, 65, 56 | |
Progesterone | H2 | 28.663 | 54.72 | 314, 272, 229, 147, 124, 91, 67 |
He | 29.599 | 358.43 | 124, 314, 272, 229, 91, 67, 147 | |
Propantheline | H2 | 24.358 | 735.98 | 86, 181, 310, 99, 152, 44, 58, 325, 127, 71 |
He | 25.183 | 3169.32 | 86, 181, 44, 99, 310, 152, 58, 325, 127, 71 | |
Propranolol | H2 | 22.279 | 745.35 | 259, 215, 144, 115, 72 |
He | 23.188 | 3138.57 | 72, 115, 144, 259, 215 | |
Quinine | H2 | 28.967 | 2199.60 | 189, 160, 136 |
He | 29.839 | 4577.02 | 136, 189, 160 | |
Ranitidine I | H2 | 21.701 | 272.14 | 235, 137, 94, 67 |
He | 22.514 | 497.94 | 137, 235, 94, 67 | |
Ranitidine II | H2 | 28.971 | 279.25 | |
He | 29.960 | 1175.13 | ||
Rimonabant | H2 | 35.656 | 601.19 | 84, 363, 55, 99, 282, 335, 299, 41, 380, 145, 462* |
He | 37.392 | 1808.45 | 84, 55, 99, 363, 282, 335, 299, 41, 380, 111*, 145 | |
Salicylamide | H2 | 12.103 | 1129.40 | 120, 137, 92, 65, 53, 44, 80 |
He | 12.979 | 457.91 | 120, 137, 92, 65, 53, 44, 80 | |
Salicylic acid | H2 | 9.100 | 1859.82 | 120, 92, 138, 64, 46 |
He | 9.655 | 1343.64 | 120, 92, 138, 64, 46 | |
Scopolamine | H2 | 24.172 | 1502.23 | 94, 138, 108, 154, 303 |
He | 25.121 | 3631.33 | 94, 138, 108, 154, 303 | |
Secobarbital | H2 | 17.809 | 2691.55 | 195, 168, 124, 97, 53 |
He | 18.684 | 1204.76 | 168, 195, 97, 124, 53 | |
Sibutramine | H2 | 18.276 | 16371.68 | 114, 72, 58, 101, 128, 137 |
He | 19.109 | 5010.93 | 114, 72, 58, 101, 128, 137 | |
Sildenafil | H2 | 45.447 | 145.57 | 404, 281*, 207, 99, 56 |
He | 49.500 | 17.60 | 99, 404, 56, 283*, 207 | |
Stanozolol | H2 | 31.003 | 163.95 | 96, 328, 257, 270, 133, 119, 175 |
He | 32.022 | 335.89 | 96, 328, 257, 270, 133, 119, 175 | |
Strychnine | H2 | 31.979 | 2444.29 | 334, 167, 130, 107, 77, 55 |
He | 33.167 | 296.67 | 334, 167, 130, 107, 77, 55 | |
Sulfadiazine | H2 | 26.540 | 512.14 | 185, 92, 65, 108 |
He | 27.429 | 756.37 | 185, 92, 65, 108 | |
Sulfadimethoxine I | H2 | 28.890 | 219.77 | 259, 140, 92, 65, 168, 108, 121, 82, 187 |
He | 29.806 | 639.59 | 259, 140, 92, 65, 168, 108, 121, 82, 187 | |
Sulfadimethoxine II | H2 | 29.269 | 364.43 | |
He | 30.114 | 208.79 | ||
Sulfamerazine | H2 | 27.012 | 801.84 | 199, 92, 65 |
He | 27.910 | 1340.67 | 200*, 199, 92, 65 | |
Sulfamethazine | H2 | 27.373 | 2275.83 | 213, 92, 65 |
He | 28.212 | 1074.36 | 214*, 213, 92, 65 | |
Sulfamethoxazole | H2 | 25.579 | 1070.19 | 92, 108, 65, 156, 119, 162, 174, 43*, 140* |
He | 26.156 | 910.57 | 92, 156, 108, 65, 162, 119, 253*, 174, 189* | |
Sulfamethoxypyridazine | H2 | 28.799 | 157.78 | 215, 92, 108, 65, 53, 80, 280 |
He | 29.673 | 214.35 | 215, 92, 65, 108, 53, 280, 80 | |
Sulfanilamide | H2 | 20.112 | 263.20 | 172, 92, 65 |
He | 20.718 | 202.79 | 172, 92, 65, 108* | |
Sulfinpyrazone | H2 | 23.429 | 761.20 | 278, 249, 209, 183, 152, 130, 105, 77, 51 |
He | 24.242 | 1169.11 | 278, 77, 105, 130, 51, 249, 209, 183, 152 | |
Sulindac | H2 | 29.207 | 198.68 | 233, 297, 312, 248, 67, 123, 47, 133, 220 |
He | 30.083 | 516.90 | 297, 233, 312, 248,123, 220, 67, 47, 133 | |
Synephrine | H2 | 15.602 | 43.68 | 135*, 44, 107, 179*, 160*, 77, 51, 91 |
He | 16.281 | 35.97 | 44, 77, 108*, 107, 65*, 51, 91 | |
Tadalafil | H2 | 41.729 | 1803.01 | 389, 262, 204, 169 |
He | 44.673 | 79.24 | 389, 262, 204, 169 | |
Terbinafine | H2 | 23.292 | 289.12 | 141, 276, 234, 115, 291, 196 |
He | 24.139 | 1216.53 | 141, 276, 115, 234, 291, 196 | |
Testosterone | H2 | 27.168 | 65.84 | 288, 246, 203, 147, 124, 91, 55 |
He | 28.115 | 328.53 | 124, 288, 246, 147, 203, 91, 55 | |
Tetracaine | H2 | 23.189 | 5752.14 | 58, 71, 176, 150, 105, 193, 92 |
He | 24.012 | 3991.85 | 58, 71, 176, 150, 105, 193, 92 | |
Theobromine | H2 | 19.022 | 23.33 | 180, 67, 109, 55, 82, 137, 42, 94 |
He | 19.157 | 142.02 | 180, 67, 55, 109, 82, 137, 42, 94 | |
Theophylline | H2 | 20.324 | 33.21 | 180, 95, 68, 53 |
He | 21.141 | 246.52 | 180, 95, 68, 53 | |
Thiodimethylsildenafil | H2 | 40.912 | 33.32 | 113, 70, 42*, 84, 328*, 343, 56 |
He | 43.571 | 48.61 | 113, 340*, 70, 84, 283*, 56, 343 | |
Thiohomosildenafil | H2 | 50.969 | 202.81 | 113, 70, 56, 475, 98, 42, 327, 341, 269, 84 |
He | 55.952 | 201.35 | 113, 70, 56, 475, 98, 42, 327, 341, 269, 84 | |
Thioridazine | H2 | 31.712 | 366.09 | 370, 244, 185, 126, 98, 70 |
He | 32.798 | 120.18 | 98, 370, 70, 185, 244, 126 | |
Thiosildenafil | H2 | 47.756 | 296.39 | 99, 448, 56, 489, 425, 70, 207 |
He | 51.652 | 355.43 | 99, 448, 56, 70, 489, 425, 207 | |
Tinidazole | H2 | 21.175 | 776.12 | 201, 123, 80, 68, 93, 107, 53, 154, 247 |
He | 21.921 | 3229.62 | 201, 53, 80, 123, 68, 93, 107, 154, 247 | |
Tolbutamide | H2 | 15.612 | 426.74 | 91, 171, 155, 65, 107, 77, 197 |
He | 16.398 | 684.97 | 91, 171, 155, 65, 107, 77, 197 | |
Vardenafil analogue | H2 | 27.628 | 5472.86 | 284, 312, 256, 67, 297, 120, 269, 93, 135 |
He | 28.462 | 2912.76 | 284, 312, 256, 297, 67, 120, 269, 93, 135 | |
Yohimbine | H2 | 32.330 | 1464.36 | 353, 169 |
He | 33.427 | 1587.82 | 353, 169 | |
Zolpidem | H2 | 28.784 | 378.38 | 235, 207, 219, 281*, 307, 65, 92, 191 |
He | 29.717 | 205.59 | 235, 307, 219, 92, 65, 191, 207 | |
Cetilistat | H2 | 13.943 | 218.91 | 177, 160, 133, 55, 104, 77, 401 |
He | 14.692 | 234.20 | 177, 160, 133, 104, 55, 77, 401 |
*represent the differences between the H2 and He ions.