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. 2018 Oct 12;8:15202. doi: 10.1038/s41598-018-33227-y

Figure 3.

Figure 3

Structural determination of Fr. 6 as glyceollin I with NMR and TOF-MS. One-dimensional 1H-NMR (A) and 13C-NMR (B) measurements of Fr. 6 were performed in methanol-d4. (C) Monoisotopic molecular ion of 337.1129 m/z corresponding to C20H17O5 as [M-H] (theoretical m/z: 337.1070) by TOF-MS analysis. (D) Chemical structure of glyceollin I.