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. 2018 Oct 9;6:461. doi: 10.3389/fchem.2018.00461

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Copyright © 2018 Maniaki, Pilichos and Perlepes.

This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

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The crystallographically established {Mn₁₂O₁₂} cores of the {Mn₁₂}, {Mn₁₂}⁻, and {Mn₁₂}²⁻ SMMs, and proposed core for the {Mn₁₂}³⁻ SMMs. The symbol represents Mn^IV, the symbol represents Mn^III, the symbol represents Mn^II, and the asterisk illustrates the triply bridging O²⁻ group (Schematic drawing inspired by Bagai and Christou, 2009). Coordination bonds are drawn in bold.

Inline graphic — The crystallographically established {Mn₁₂O₁₂} cores of the {Mn₁₂}, {Mn₁₂}⁻, and {Mn₁₂}²⁻ SMMs, and proposed core for the {Mn₁₂}³⁻ SMMs. The symbol represents Mn^IV, the symbol represents Mn^III, the symbol represents Mn^II, and the asterisk illustrates the triply bridging O²⁻ group (Schematic drawing inspired by Bagai and Christou, 2009). Coordination bonds are drawn in bold.