Table 1. Binding Energies of Fitted Components for the N 1s Photoelectron Spectrac.
| binding energy (eV) of component |
|||
|---|---|---|---|
| A | B | C | |
| 9HAde | 398.49 | 399.14 (+0.65)a | 400.06 (+1.57)a |
| SION-31 | 399.10 | 399.10 (+0.00)a | 400.59 (+1.49)a |
| SION-32 | 399.17 | 399.49 (+0.32)a | 400.58 (+1.41)a |
| SION-33 | 399.12 | 400.08 (+0.96)a | 400.94 (+1.82)a |
| SION-34 | 399.04b | 400.69 (+1.65)a | 400.69 (+1.65)a |
| SION-35 | 399.07 | 399.08 (+0.01)a | 400.32 (+1.25)a |
Values in brackets are the differences of binding energy from component A.
For SION-34, the component A includes the N atoms in the pzdc3– ligand.
Components A, B, and C were constrained to have the same FWHM, and the peak areas were constrained in the ratio A:B:C of 3:1:1.