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. 2018 Feb 1;57(4):1888–1900. doi: 10.1021/acs.inorgchem.7b02761

Table 1. Binding Energies of Fitted Components for the N 1s Photoelectron Spectrac.

  binding energy (eV) of component
A B C
9HAde 398.49 399.14 (+0.65)a 400.06 (+1.57)a
SION-31 399.10 399.10 (+0.00)a 400.59 (+1.49)a
SION-32 399.17 399.49 (+0.32)a 400.58 (+1.41)a
SION-33 399.12 400.08 (+0.96)a 400.94 (+1.82)a
SION-34 399.04b 400.69 (+1.65)a 400.69 (+1.65)a
SION-35 399.07 399.08 (+0.01)a 400.32 (+1.25)a
a

Values in brackets are the differences of binding energy from component A.

b

For SION-34, the component A includes the N atoms in the pzdc3– ligand.

c

Components A, B, and C were constrained to have the same FWHM, and the peak areas were constrained in the ratio A:B:C of 3:1:1.