. 2018 Feb 1;57(4):1888–1900. doi: 10.1021/acs.inorgchem.7b02761

Table 2. Bond Angles (in Degrees) Calculated from the Crystal Structures of SION-31, SION-32, SION-33, SION-34, and SION-35.

	C6–N1–C2	C2–N3–C4	C5–N7–C8	C4–N9–C8
SION-31	119.8(2)	112.9(2)^a	103.1(2)^a	103.7(2)^a
SION-32	118.1(13)	117.4(14)	110.2^a^,^b	106.1^a^,^b
SION-33	118.3(7)	111.5(8)^a	106.5(7)	104.6(7)^a
SION-34	124.6(3)	113.7(3)	102.9(3)^a	103.2(3)^a
SION-35	119.5(4)	112.0(4)	104.3(3)^a	104.8(3)^a

Metal coordinated to the N atom.

Angles modeled as part of an idealized 5-membered ring.