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. 2018 Feb 1;57(4):1888–1900. doi: 10.1021/acs.inorgchem.7b02761

Table 4. Regularities in the C–N–C Angle Values of Adenine Ligand within the Adenine-MOF Crystal Structures Reported in the Literature.

  N site nonprotonated N site protonated
C2–N1–C6 119 ± 4° 124 ± 1°
C2–N3–C4 112 ± 2° NA
C5–N7–C8 103 ± 1° 107 ± 2°
C4–N9–C8 103 ± 1° 106 ± 1°