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. Author manuscript; available in PMC: 2018 Oct 22.
Published in final edited form as: Acc Chem Res. 2018 Sep 20;51(10):2391–2399. doi: 10.1021/acs.accounts.8b00319

Scheme 2. Thermodynamic Cycles (Square Schemes) and Equations for BDFEs of (A) a Single PCET Reagent and (B) a Reductant/Acid Pairaa.

Scheme 2.

aThe CG,sol constant is in essence ΔG°(H+ + e−→ H) in solvent “sol”. Adapted with permission from ref 13. Copyright 2012 Royal Society of Chemistry.