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. 2018 Feb 2;10(2):35. doi: 10.1007/s40820-018-0189-1

Table 4.

Chronological details of the evolution of micro-/nano-cantilever sensors

Authors and year Material set Constituent layers Readout technique Comments
Binning et al. (1986) Cantilever Au, tip diamond Structural layer: Au Tunneling current AFM topological measurement
Gimzewski et al. (1993) Cantilever Si, Al + Pt coating Additional layer: Al + Pt Optical Calorimeter-based chemical sensing
Thundat et al. (1994) Cantilever Si/Si3N4 + Au/Al coating

Additional layer: Au/Al

Structural layer: Si/Si3N4

Optical Humidity and mercury vapor sensing
Raiteri et al. (1995) Cantilever Si3N4 + Au/Pt coating

Structural layer: Si3N4

Additional layer: Au/Pt

Optical Measurement of electrochemically induced surface stress
Boisen et al. (2000) Cantilever Si, piezoresistor doped Si

Immobilization layer: gold/polymer

Protective layer: SiO2

Piezoresistive layer: p-poly-Si

Isolation layer: SiO2

Structural layer: Si

Piezoresistive Temperature, humidity, and alcohol sensing
Thaysen et al. (2002) Cantilever SU-8, piezoresistor Au

Immobilization + isolation layer: SU-8,

Piezoresistor layer: Au

Structural layer: SU-8

Piezoresistive Surface micro-machining
Rasmussen et al. (2003) Cantilever Si3N4, piezoresistor doped polysilicon

Immobilization layer: Au

Isolation layer: SiNx

Piezoresistor layer: p-poly-Si,

Structural layer: SiNx

Piezoresistive

ssDNA sensing

Bulk + surface micro-machining

Gammelgaard et al. (2006) Cantilever SU-8, piezoresistor CB SU-8

Isolation layer: SU-8

Piezoresistor layer: CB SU-8

Structural layer: SU-8

Piezoresistive Surface micro-machining
Zuo et al. (2006) Cantilever SiO2, piezoresistor p-SCS

Immobilization layer: Au

Isolation layer: SiO2

Piezoresistor layer: p-SCS

Structural layer: SiO2

Piezoresistive

Methyl-phosphonate sensing

Bulk micro-machining

Kale et al. (2009) Cantilever SU-8, piezoresistor p-poly-Si

Immobilization + isolation layer: SU-8

Piezoresistive layer: p-poly-Si,

Structural layer: SU-8

Piezoresistive Surface micro-machining, HWCVD
Seena et al. (2009) Cantilever SU-8, piezoresistor CB SU-8

Immobilization + isolation layer: SU-8

Piezoresistive layer: CB SU-8

Structural layer: SU-8

Piezoresistive Surface micro-machining
Reddy et al. (2012) Cantilever SU-8, piezoresistor CB SU-8

Immobilization + isolation layer: SU-8

Piezoresistive layer: CB SU-8

Structural layer: SU-8

Piezoresistive

CO sensing

Surface micro-machining

Patil et al. (2014) Cantilever SU-8, piezoresis or CB SU-8

Immobilization + isolation layer: SU-8

Piezoresistor layer: CB SU-8

Structural layer: SU-8

Prohibition layer: Au

Piezoresistive

Soil moisture and relative humidity (RH) sensing

Surface micro-machining