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. 2018 Oct 10;20(41):26362–26371. doi: 10.1039/c8cp05473h

Table 1. SABRE efficiency values for the indicated resonances of the specified analytes as determined by eqn (9) and the lines of best fit in Fig. 4–6 .

Analyte (R2) Catalyst NHC (R1) SABRE-Relay carrier NMR detection field T (MHz) SABRE efficiency (E) (%)
Pyridine IMes N/A 9.4 (400) 2,6-H (ortho) 6.5 ± 0.1
3,5-H (meta) 3.9 ± 0.1
4-H (para) 6.0 ± 0.1
4-Methylpyridine IMes N/A 9.4 (400) 2,6-H (ortho) 6.4 ± 0.2
3,5-H (meta) 3.7 ± 0.1
4-CH3 (methyl) 0.93 ± 0.04
Methyl-4,6-d2-nicotinate IMes N/A 9.4 (400) 2-H (ortho) 13.6 ± 0.1
5-H (meta) 15.9 ± 0.3
Methyl-4,6-d2-nicotinate d 22-IMes N/A 9.4 (400) 2-H (ortho) 19.4 ± 0.3
5-H (meta) 21.7 ± 0.5
Methyl-4,6-d2-nicotinate IMes N/A 1.0 (43) 2-H (ortho) 12.3 ± 0.2
5-H (meta) 15.9 ± 0.2
1-Propanol IMes NH3 9.4 (400) 1-OH 0.57 ± 0.03
1-CH2 0.95 ± 0.05
2-CH2 0.57 ± 0.03
3-CH3 0.73 ± 0.03